ReviewThe journal of physical chemistry. C, Nanomaterials and interfaces2023
Photocatalysis of Metallic Nanoparticles: Interband vs Intraband Induced Mechanisms.
Review in The journal of physical chemistry. C, Nanomaterials and interfaces, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 16 papers.
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Who cites it
16 citing papers in PubMed.
- Photocatalysis beyond band gaps and hot carriers: toward a unified view of semiconductor and plasmonic systems.Chemical science · 2026Review
- Interfacial Role of DopantNanophotonics (Berlin, Germany) · 2026Article
- Morphology-modified contributions of electronic transitions to the optical response of plasmonic nanoporous gold metamaterial.Nature communications · 2026Article
- Tailoring Ag-Pt nanoalloys through solid-state dewetting: structural and optical insights.Beilstein journal of nanotechnology · 2026Article
- Green Nanoparticles for Enhanced Electrochemical Monitoring of Pharmaceutical Contaminants: Comparative Investigation Between Monometallic and Bimetallic Nanoparticles.Micromachines · 2025Article
- Review
- Review
- The dynamics of plasmon-induced hot carrier creation in colloidal gold.Nature communications · 2025Article
- Facile synthesis of copper, nickel and their bimetallic nanoparticles: optical and structural characterization.Discover nano · 2025Article
- Deciphering the Photocatalysis Mechanism of Semimetallic Bismuth Nanoparticles.The journal of physical chemistry. C, Nanomaterials and interfaces · 2024Article
- Interband and Intraband Hot Carrier-Driven Photocatalysis on Plasmonic Bimetallic Nanoparticles: A Case Study of Au-Cu Alloy Nanoparticles.ACS nanoscience Au · 2024Article
- Sustainable and Reusable Modified Membrane Based on Green Gold Nanoparticles for Efficient Methylene Blue Water Decontamination by a Photocatalytic Process.Nanomaterials (Basel, Switzerland) · 2024Article
- The paradox of thermal vs. non-thermal effects in plasmonic photocatalysis.Nature communications · 2024Review
- From Precious to Earth-Abundant Metallic Nanoparticles: A Trend of Interband Transitions in Photocatalyzed Nitrobenzene Reduction.The journal of physical chemistry. C, Nanomaterials and interfaces · 2024Article
- Decoupling Plasmonic Hot Carrier from Thermal Catalysis via Electrode Engineering.Nano letters · 2024Article
- Peculiarities of the Structure of Au-TiOMaterials (Basel, Switzerland) · 2023Article
Corrections and comments
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Authors and funding
3 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Photocatalysis induced by localized surface plasmon resonance of metallic nanoparticles has been studied for more than a decade, but photocatalysis originating from direct interband excitations is still under-explored. The spectral overlap and the coupling of these two optical regimes also complicate the determination of hot carriers' energy states and eventually hinder the accurate assignment of their catalytic role in studied reactions. In this Featured Article, after reviewing previous studies, we suggest classifying the photoexcitation via intra- and interband transitions where the physical states of hot carriers are well-defined. Intraband transitions are featured by creating hot electrons above the Fermi level and suitable for reductive catalytic pathways, whereas interband transitions are featured by generating hot d-band holes below the Fermi level and better for oxidative catalytic pathways. Since the contribution of intra- and interband transitions are different in the spectral regions of localized surface plasmon resonance and direct interband excitations, the wavelength dependence of the photocatalytic activities is very helpful in assigning which transitions and carriers contribute to the observed catalysis.
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Registered trials
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