Evidence map›Paper›PMID 37604905›Full record

ArticleNature communications2023

Allosteric control of olefin isomerization kinetics via remote metal binding and its mechanochemical analysis.

Yichen Yu, Robert T O'Neill, Roman Boulatov, Ross A Widenhoefer, Stephen L Craig

Open access · goldAbstract read
In one paragraph

Article in Nature communications, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.

0numbers the graph read from it
0cells of the map it votes in
4citing papers in PubMed
1.6field-weighted citation impact, top 17% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

4 citing papers in PubMed, 8 citations in OpenAlex.

  1. Article
  2. Article
  3. Mechanochemical Approaches to Fundamental Studies in Soft-Matter Physics.Angewandte Chemie (International ed. in English) · 2024
    Review
  4. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors at 2 institutions in 2 countries.

Yichen Yu *Department of Chemistry, Duke University, Durham, NC, 27708, USA.
Robert T O'Neill *Department of Chemistry, University of Liverpool, Crown Street, Liverpool, L69 7ZD, UK.ORCID http://orcid.org/0000-0002-4348-7635
Roman BoulatovDepartment of Chemistry, University of Liverpool, Crown Street, Liverpool, L69 7ZD, UK. boulatov@liverpool.ac.uk.ORCID http://orcid.org/0000-0002-7601-4279
Ross A WidenhoeferDepartment of Chemistry, Duke University, Durham, NC, 27708, USA. ross.widenhoefer@duke.edu.
Stephen L CraigDepartment of Chemistry, Duke University, Durham, NC, 27708, USA. stephen.craig@duke.edu.ORCID http://orcid.org/0000-0002-8810-0369
Duke University · USUniversity of Liverpool · GB

Funding

ACS | American Chemical Society Petroleum Research Fund (ACS Petroleum Research Fund) 57757-ND3ACS | American Chemical Society Petroleum Research Fund (ACS Petroleum Research Fund) 58885-ND7National Science Foundation (NSF) CHE-1808518U.S. Department of Energy (DOE) DE-SC0018188
6 · The paper itself

Abstract

Allosteric control of reaction thermodynamics is well understood, but the mechanisms by which changes in local geometries of receptor sites lower activation reaction barriers in electronically uncoupled, remote reaction moieties remain relatively unexplored. Here we report a molecular scaffold in which the rate of thermal E-to-Z isomerization of an alkene increases by a factor of as much as 10

Identifiers

PMID37604905
PMCPMC10442431
OpenAlexW4386033627

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.