ArticleChemical science2023
A dinuclear Rh(-i)/Rh(i) complex bridged by biphilic phosphinine ligands.
Article in Chemical science, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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Who cites it
3 citing papers in PubMed, 10 citations in OpenAlex.
- Dynamic Reactivity: Reversible Reaction of a Phosphinine-Borane Adduct With Water and Double Hydrophosphination.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Dithienoarsinines: stable and planar π-extended arsabenzenes.Chemical science · 2025Article
- Highly selective, reversible water activation by P,N-cooperativity in pyridyl-functionalized phosphinines.Chemical science · 2024Article
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Authors and funding
4 authors at 1 institution in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Bimetallic complexes have enabled precise control of catalysis by accumulating two discrete metal centres. In these complexes, bridging ligands are essential to combine multiple metals into one molecule. Among some bridging modes, an unsymmetric bridging mode will differentiate the electronic structures of the two metal centres. In this study, a dinuclear Rh(-i)/Rh(i) complex bridged by tridentate phosphine-phosphinine-phosphine ligands was prepared by reduction of the corresponding Rh(i) complex. Single-crystal X-ray analysis and DFT calculations suggest that the phosphinine ligands adopt an unsymmetric bridging mode wherein phosphinine accepts d-electrons from one Rh centre and, at the same time, donates lone pairs to the other Rh centre.
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Registered trials
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