Evidence map›Paper›PMID 37592989›Full record

ArticleChemical science2023

"Mn-locking" effect by anionic coordination manipulation stabilizing Mn-rich phosphate cathodes.

Wei Zhang, Yulun Wu, Yuhang Dai, Zhenming Xu, Liang He, Zheng Li, Shihao Li, Ruwei Chen, Xuan Gao, Wei Zong and 11 more

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Chemical science, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

  1. Article
  2. Article
  3. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

21 authors.

Wei ZhangSchool of Metallurgy and Environment, Engineering Research Center of the Ministry of Education for Advanced Battery Materials, Hunan Provincial Key Laboratory of Nonferrous Value-Added Metallurgy, Central South University Changsha 410083 P. R. China zhangzhian@csu.edu.cn laiyanqing@csu.edu.cn.ORCID https://orcid.org/0000-0001-6888-3338
Yulun WuSchool of Metallurgy and Environment, Engineering Research Center of the Ministry of Education for Advanced Battery Materials, Hunan Provincial Key Laboratory of Nonferrous Value-Added Metallurgy, Central South University Changsha 410083 P. R. China zhangzhian@csu.edu.cn laiyanqing@csu.edu.cn.
Yuhang DaiElectrochemical Innovation Lab (EIL), Department of Chemical Engineering, University College London London WC1E 7JE UK g.he@ucl.ac.uk.ORCID https://orcid.org/0000-0001-8445-6758
Zhenming XuJiangsu Key Laboratory of Electrochemical Energy Storage Technologies, College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics Nanjing 210016 P. R. China xuzhenming@nuaa.edu.cn.ORCID https://orcid.org/0000-0002-7039-3845
Liang HeSchool of Metallurgy and Environment, Engineering Research Center of the Ministry of Education for Advanced Battery Materials, Hunan Provincial Key Laboratory of Nonferrous Value-Added Metallurgy, Central South University Changsha 410083 P. R. China zhangzhian@csu.edu.cn laiyanqing@csu.edu.cn.
Zheng LiSchool of Metallurgy and Environment, Engineering Research Center of the Ministry of Education for Advanced Battery Materials, Hunan Provincial Key Laboratory of Nonferrous Value-Added Metallurgy, Central South University Changsha 410083 P. R. China zhangzhian@csu.edu.cn laiyanqing@csu.edu.cn.
Shihao LiSchool of Metallurgy and Environment, Engineering Research Center of the Ministry of Education for Advanced Battery Materials, Hunan Provincial Key Laboratory of Nonferrous Value-Added Metallurgy, Central South University Changsha 410083 P. R. China zhangzhian@csu.edu.cn laiyanqing@csu.edu.cn.
Ruwei ChenChristopher Ingold Laboratory, Department of Chemistry, University College London London WC1H 0AJ UK i.p.parkin@ucl.ac.uk.
Xuan GaoChristopher Ingold Laboratory, Department of Chemistry, University College London London WC1H 0AJ UK i.p.parkin@ucl.ac.uk.
Wei ZongChristopher Ingold Laboratory, Department of Chemistry, University College London London WC1H 0AJ UK i.p.parkin@ucl.ac.uk.ORCID https://orcid.org/0000-0002-1815-6471
Fei GuoElectrochemical Innovation Lab (EIL), Department of Chemical Engineering, University College London London WC1E 7JE UK g.he@ucl.ac.uk.
Jiexin ZhuElectrochemical Innovation Lab (EIL), Department of Chemical Engineering, University College London London WC1E 7JE UK g.he@ucl.ac.uk.
Haobo DongElectrochemical Innovation Lab (EIL), Department of Chemical Engineering, University College London London WC1E 7JE UK g.he@ucl.ac.uk.
Jianwei LiChristopher Ingold Laboratory, Department of Chemistry, University College London London WC1H 0AJ UK i.p.parkin@ucl.ac.uk.
Chumei YeDepartment of Materials Science and Metallurgy, University of Cambridge Cambridge CB3 0FS UK.
Simin LiSchool of Metallurgy and Environment, Engineering Research Center of the Ministry of Education for Advanced Battery Materials, Hunan Provincial Key Laboratory of Nonferrous Value-Added Metallurgy, Central South University Changsha 410083 P. R. China zhangzhian@csu.edu.cn laiyanqing@csu.edu.cn.
Feixiang WuSchool of Metallurgy and Environment, Engineering Research Center of the Ministry of Education for Advanced Battery Materials, Hunan Provincial Key Laboratory of Nonferrous Value-Added Metallurgy, Central South University Changsha 410083 P. R. China zhangzhian@csu.edu.cn laiyanqing@csu.edu.cn.ORCID https://orcid.org/0000-0002-9688-2428
Zhian ZhangSchool of Metallurgy and Environment, Engineering Research Center of the Ministry of Education for Advanced Battery Materials, Hunan Provincial Key Laboratory of Nonferrous Value-Added Metallurgy, Central South University Changsha 410083 P. R. China zhangzhian@csu.edu.cn laiyanqing@csu.edu.cn.ORCID https://orcid.org/0000-0002-8691-6006
Guanjie HeChristopher Ingold Laboratory, Department of Chemistry, University College London London WC1H 0AJ UK i.p.parkin@ucl.ac.uk.ORCID https://orcid.org/0000-0002-7365-9645
Yanqing LaiSchool of Metallurgy and Environment, Engineering Research Center of the Ministry of Education for Advanced Battery Materials, Hunan Provincial Key Laboratory of Nonferrous Value-Added Metallurgy, Central South University Changsha 410083 P. R. China zhangzhian@csu.edu.cn laiyanqing@csu.edu.cn.
Ivan P ParkinChristopher Ingold Laboratory, Department of Chemistry, University College London London WC1H 0AJ UK i.p.parkin@ucl.ac.uk.ORCID https://orcid.org/0000-0002-4072-6610

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

High-voltage cathodes with high power and stable cyclability are needed for high-performance sodium-ion batteries. However, the low kinetics and inferior capacity retention from structural instability impede the development of Mn-rich phosphate cathodes. Here, we propose light-weight fluorine (F) doping strategy to decrease the energy gap to 0.22 eV from 1.52 eV and trigger a "Mn-locking" effect-to strengthen the adjacent chemical bonding around Mn as confirmed by density functional theory calculations, which ensure the optimized Mn ligand framework, suppressed Mn dissolution, improved structural stability and enhanced electronic conductivity. The combination of

Identifiers

PMID37592989
PMCPMC10430554

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.