ArticleNature communications2023
Pillararene incorporated metal-organic frameworks for supramolecular recognition and selective separation.
Article in Nature communications, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 12 papers.
What it found
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Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
12 citing papers in PubMed.
- Rational guest selection: a general principle for stabilizing multi-component luminescent materials.Chemical science · 2026Article
- Synthesis and guest inclusion for molecular catcher-based structure determination.Nature protocols · 2026Review
- Photo Capture of Water by Single Crystals of a Nonporous Metal-Organic Material.Journal of the American Chemical Society · 2026Article
- A state-switchable TADF macrocycle for multi-analyte sensing and hydrogen gas-driven emission enhancement.Communications chemistry · 2026Article
- Hydrogen-bonded supramolecular polymer networks for effective removal of perchlorate in water via clustered hydrogen-bonding.Nature communications · 2025Article
- Bionic Artificial Leaves Based on AIE-Active Supramolecular Hydrogel for Efficient Photocatalysis.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Article
- Structural insights into 1,4-bis-(neopent-yloxy)pillar[5]arene and the pyridine host-guest system.IUCrData · 2024Article
- Ionic Bent-Core Pillar[Chemistry of materials : a publication of the American Chemical Society · 2024Article
- Accurate construction of monolayer, bilayer, sandwich bilayer, four-layer, multi-layer and chiral bilayer 2D pillararene-type supramolecular networks.Chemical science · 2024Article
- Review
- Metal-Organic Frameworks: Versatile Platforms for Biomedical Innovations.Materials (Basel, Switzerland) · 2023Review
Corrections and comments
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Authors and funding
8 authors.
Funding
Abstract
Crystalline frameworks containing incorporated flexible macrocycle units can afford new opportunities in molecular recognition and selective separation. However, such functionalized frameworks are difficult to prepare and challenging to characterize due to the flexible nature of macrocycles, which limits the development of macrocycle-based crystalline frameworks. Herein, we report the design and synthesis of a set of metal-organic frameworks (MOFs) containing pillar[5]arene units. The pillar[5]arene units were uniformly embedded in the periodic frameworks. Single crystal X-ray diffraction analysis revealed an interpenetrated network that appears to hinder the rotation of the pillar[5]arene repeating units in the frameworks, and it therefore resulted in the successful determination of the precise pillar[5]arene host structure in a MOF crystal. These MOFs can recognize paraquat and 1,2,4,5-tetracyanobenzene in solution and selectively remove trace pyridine from toluene with relative ease. The work presented here represents a critical step towards the synthesis of macrocycle-incorporated crystalline frameworks with well-defined structures and functional utility.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.