ArticleInorganic chemistry2023
Resonant Excitation Unlocks Chemical Selectivity of Platinum Lβ Valence-to-Core X-ray Emission Spectra.
Article in Inorganic chemistry, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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Who cites it
3 citing papers in PubMed.
- Fourteen-analyser high-resolution hard X-ray emission spectrometer at I20 beamline at Diamond Light Source.Journal of synchrotron radiation · 2026Article
- Metal-ligand covalency of C-H activating iridium complexes from L-edge valence-to-core resonant inelastic X-ray scattering.Chemical science · 2026Article
- Evaluating Palladium 4d-to-2p X-ray Emission Spectroscopy for Characterizing Catalytically Relevant Species.Inorganic chemistry · 2026Article
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2 authors.
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Abstract
Valence-to-core X-ray emission spectroscopy (VtC XES) is an emerging technique that uses hard X-rays to probe the valence electronic structure of an absorbing atom. Despite finding varied applications for light elements and first row transition metals, little work has been done on heavier elements such as second and third row transition metals. This lack of application is at least partially due to the relatively low resolution of the data at the high energies required to measure these elements, which obscures the useful chemical information that can be extracted from the lower energy, higher resolution spectra of lighter elements. Herein, we collect data on a set of platinum-containing compounds and demonstrate that the VtC XES resolution can be dramatically enhanced by exciting the platinum atom in resonance with its L
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