Evidence map›Paper›PMID 37571167›Full record

ArticlePolymers2023

Chemical Recycling of PET Using Catalysts from Layered Double Hydroxides: Effect of Synthesis Method and Mg-Fe Biocompatible Metals.

Ana P Arcanjo, Denisson O Liborio, Santiago Arias, Florival R Carvalho, Josivan P Silva, Bernardo D Ribeiro, Marcos L Dias, Aline M Castro, Roger Fréty, Celmy M B M Barbosa and 1 more

Open access · goldAbstract read
In one paragraph

Article in Polymers, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
1.1field-weighted citation impact, top 27% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed, 11 citations in OpenAlex.

  1. Article
  2. Review
  3. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

11 authors at 3 institutions in 1 country.

Ana P ArcanjoLaboratory of Refining and Cleaner Technology (LabRefino-Lateclim), Department of Chemical Engineering, Institute for Petroleum and Energy Research (i-LITPEG), Federal University of Pernambuco, Recife 50740-550, PE, Brazil.
Denisson O LiborioLaboratory of Refining and Cleaner Technology (LabRefino-Lateclim), Department of Chemical Engineering, Institute for Petroleum and Energy Research (i-LITPEG), Federal University of Pernambuco, Recife 50740-550, PE, Brazil.
Santiago AriasLaboratory of Refining and Cleaner Technology (LabRefino-Lateclim), Department of Chemical Engineering, Institute for Petroleum and Energy Research (i-LITPEG), Federal University of Pernambuco, Recife 50740-550, PE, Brazil.ORCID 0000-0002-7811-7722
Florival R CarvalhoFuel Laboratory, Department of Chemical Engineering, Institute for Petroleum and Energy Research (i-LITPEG), Federal University of Pernambuco, Recife 50740-550, PE, Brazil.
Josivan P SilvaLaboratory of Refining and Cleaner Technology (LabRefino-Lateclim), Department of Chemical Engineering, Institute for Petroleum and Energy Research (i-LITPEG), Federal University of Pernambuco, Recife 50740-550, PE, Brazil.
Bernardo D RibeiroBiochemical Engineering Department, School of Chemistry, Federal University of Rio de Janeiro, Rio de Janeiro 21941-909, RJ, Brazil.ORCID 0000-0001-8621-156X
Marcos L DiasMacromolecules Institute, Federal University of Rio de Janeiro, Rio de Janeiro 21941-598, RJ, Brazil.ORCID 0000-0003-1891-7530
Aline M CastroResearch, Development and Innovation Center (Cenpes), Petrobras, Rio de Janeiro 21941-915, RJ, Brazil.ORCID 0000-0002-1355-8455
Roger FrétyLaboratory of Refining and Cleaner Technology (LabRefino-Lateclim), Department of Chemical Engineering, Institute for Petroleum and Energy Research (i-LITPEG), Federal University of Pernambuco, Recife 50740-550, PE, Brazil.ORCID 0000-0002-4532-2105
Celmy M B M BarbosaLaboratory of Refining and Cleaner Technology (LabRefino-Lateclim), Department of Chemical Engineering, Institute for Petroleum and Energy Research (i-LITPEG), Federal University of Pernambuco, Recife 50740-550, PE, Brazil.
Jose Geraldo A PachecoLaboratory of Refining and Cleaner Technology (LabRefino-Lateclim), Department of Chemical Engineering, Institute for Petroleum and Energy Research (i-LITPEG), Federal University of Pernambuco, Recife 50740-550, PE, Brazil.ORCID 0000-0002-8812-5021
Universidade Federal de Pernambuco · BRUniversidade Federal do Rio de Janeiro · BRPetrobras (Brazil) · BR

Funding

Fundação de Amparo à Ciência e Tecnologia de Pernambuco IBPG-0461-3.06/18National Council for Scientific and Technological Development 312387/2022-9Petrobras (Brazil) 0050.0078506.12.9 and 0050.0087478.13.9
6 · The paper itself

Abstract

The chemical recycling of poly(ethylene terephthalate) (PET) residues was performed via glycolysis with ethylene glycol (EG) over Mg-Fe and Mg-Al oxide catalysts derived from layered double hydroxides. Catalysts prepared using the high supersaturation method (h.s.c.) presented a higher surface area and larger particles, but this represented less PET conversion than those prepared by the low supersaturation method (l.s.c.). This difference was attributed to the smaller mass transfer limitations inside the (l.s.c.) catalysts. An artificial neural network model well fitted the PET conversion and bis(2-hydroxyethyl) terephthalate (BHET) yield. The influence of Fe in place of Al resulted in a higher PET conversion of the Mg-Fe-h.s.c. catalyst (~95.8%) than of Mg-Al-h.s.c. (~63%). Mg-Fe catalysts could be reused four to five times with final conversions of up to 97% with reaction conditions of EG: PET = 5:1 and catalyst: PET = 0.5%. These results confirm the Mg-Fe oxides as a biocompatible novel catalyst for the chemical recycling of PET residues to obtain non-toxic BHET for further polymerization, and use in food and beverage packaging.

Indexed as

BHETdepolymerizationglycolysishydrotalciteoxide catalystsplastic

Identifiers

PMID37571167
PMCPMC10422272
OpenAlexW4385490827

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.