ArticleNature communications2023
Hybridization of short-range and long-range charge transfer excited states in multiple resonance emitter.
Article in Nature communications, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 11 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
11 citing papers in PubMed.
- Selenophene π-Core Fusion for Simultaneous Fast Reverse Intersystem Crossing and Narrowband Long-Wavelength TADF.Angewandte Chemie (International ed. in English) · 2026Article
- One Molecular Platform, Three Distinct Narrowband Organoboron TADF Emitters: A Divergent One-Pot Strategy From Green to Red.Angewandte Chemie (International ed. in English) · 2026Article
- Machine-Learning-Guided Discovery of Boron-Free Narrowband Blue Thermally Activated Delayed Fluorescence Emitters.Angewandte Chemie (International ed. in English) · 2026Article
- Precise Multi-Site Borylation Engineering of Indolo[2,3-c]Carbazole-Bridged Narrowband MR-TADF Emitters.Angewandte Chemie (International ed. in English) · 2026Article
- Unraveling emission narrowing pathways in N-embedded polyaromatic systemsChemical science · 2026Article
- Systematic Engineering of Acceptor Substituents in Blue TADF Emitters for Optimized Excited-State Dynamics and OLED Performance.ACS omega · 2026Article
- Tellurophene-Induced Triplet-Singlet Spin-Flip Acceleration: An Advanced Design for Narrowband Organoboron Emitters with Fast Reverse Intersystem Crossing.Angewandte Chemie (International ed. in English) · 2026Article
- High-performance narrowband blue electroluminescence with EQE approaching 20% based on hybridized local and charge-transfer multi-resonant molecules.Chemical science · 2026Article
- Blue-to-Green Fine-Tunable Narrowband Delayed Fluorescence in Peripherally Dendritic Modified Bis-Indolocarbazoles.Angewandte Chemie (International ed. in English) · 2025Article
- Highly efficient pure-blue organic light-emitting diodes based on rationally designed heterocyclic phenophosphazinine-containing emitters.Nature communications · 2024Article
- An Ideal Molecular Construction Strategy for Ultra-Narrow-Band Deep-Blue Emitters: Balancing Bathochromic-Shift Emission, Spectral Narrowing, and Aggregation Suppression.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
Corrections and comments
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Authors and funding
6 authors.
Funding
Abstract
Multiple resonance (MR) thermally activated delayed fluorescence emitters have been actively studied as pure blue dopants for organic light-emitting diodes (OLEDs) because of excellent color purity and high efficiency. However, the reported MR emitter, 2,5,13,16-tetra-tert-butylindolo[3,2,1-jk]indolo[1',2',3':1,7]indolo[2,3-b]carbazole (tDIDCz) based on bis-fused indolocarbazole framework could not demonstrate efficient triplet-to-singlet spin crossover. In this work, we report two isomeric MR emitters designed to promote triplet exciton harvesting by reconstructing the electronic structure of tDIDCz. To manage excited states, strong electron donors were introduced at the 2,5-/1,6-position of tDIDCz. As a result, 2,5-positions managed tDIDCz shows long-range charge transfer characteristics while preserving the MR nature. Quantum chemical calculation demonstrates direct spin-orbit coupling by long-range charge transfer and spin-vibronic coupling assisted reverse intersystem crossing by short-range charge transfer simultaneously contribute to triplet-to-singlet spin crossover. Consequently, high performance blue OLED recorded a high external quantum efficiency of 30.8% at a color coordinate of (0.13, 0.13).
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.