ArticleNature communications2023
Orbital-symmetry effects on magnetic exchange in open-shell nanographenes.
Article in Nature communications, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 11 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
11 citing papers in PubMed.
- A dual-mode large language model assistant for on-surface reactionsChemical science · 2026Article
- Scanning Tunnelling Microscopy Study of Spin Interactions in Transition-Metal Phthalocyanine Adsorbates: Mechanisms, Signatures, and Control Strategies.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Review
- Ultra-long-range spin coupling in graphene revealed by atomically resolved spin excitations.Nature communications · 2026Article
- Spin State in Au Porphyrins Modulated by Charge Transfer on Au(111).Journal of the American Chemical Society · 2026Article
- On-Surface Synthesis of a Ferromagnetic Molecular Spin Trimer.Journal of the American Chemical Society · 2025Article
- A Route toward the On-Surface Synthesis of Organic Ferromagnetic Quantum Spin Chains.Journal of the American Chemical Society · 2025Article
- Magnetic Excitations in Ferromagnetically Coupled Spin-1 Nanographenes.Angewandte Chemie (International ed. in English) · 2024Article
- Atomically Precise Control of Topological State Hybridization in Conjugated Polymers.ACS nano · 2024Article
- Beyond Spin Models in Orbitally Degenerate Open-Shell Nanographenes.Nano letters · 2024Article
- Designer Spin Models in Tunable Two-Dimensional Nanographene Lattices.Nano letters · 2024Article
- Cycl[2,2,4]azine-embedded non-alternant nanographenes containing fused antiaromatic azepine ring.Chemical science · 2024Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
10 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Open-shell nanographenes appear as promising candidates for future applications in spintronics and quantum technologies. A critical aspect to realize this potential is to design and control the magnetic exchange. Here, we reveal the effects of frontier orbital symmetries on the magnetic coupling in diradical nanographenes through scanning probe microscope measurements and different levels of theoretical calculations. In these open-shell nanographenes, the exchange energy exhibits a remarkable variation between 20 and 160 meV. Theoretical calculations reveal that frontier orbital symmetries play a key role in affecting the magnetic coupling on such a large scale. Moreover, a triradical nanographene is demonstrated for investigating the magnetic interaction among three unpaired electrons with unequal magnetic exchange, in agreement with Heisenberg spin model calculations. Our results provide insights into both theoretical design and experimental realization of nanographene materials with different exchange interactions through tuning the orbital symmetry, potentially useful for realizing magnetically operable graphene-based nanomaterials.
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.