Evidence map›Paper›PMID 37553368›Full record

ArticleNature communications2023

Development of high-voltage and high-energy membrane-free nonaqueous lithium-based organic redox flow batteries.

Rajeev K Gautam, Xiao Wang, Amir Lashgari, Soumalya Sinha, Jack McGrath, Rabin Siwakoti, Jianbing Jimmy Jiang

Abstract read
In one paragraph

Article in Nature communications, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.

0numbers the graph read from it
0cells of the map it votes in
7citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

7 citing papers in PubMed.

  1. Article
  2. Review
  3. Article
  4. Article
  5. Article
  6. Boosting the cell voltage in biphasic flow batteriesPhysical chemistry chemical physics : PCCP · 2024
    Article
  7. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Rajeev K GautamDepartment of Chemistry, University of Cincinnati, P.O. Box 210172, Cincinnati, OH, 45221, USA.
Xiao WangDepartment of Chemistry, University of Cincinnati, P.O. Box 210172, Cincinnati, OH, 45221, USA.
Amir LashgariDepartment of Chemistry, University of Cincinnati, P.O. Box 210172, Cincinnati, OH, 45221, USA.ORCID http://orcid.org/0000-0001-5976-4871
Soumalya SinhaDepartment of Chemistry, University of Cincinnati, P.O. Box 210172, Cincinnati, OH, 45221, USA.ORCID http://orcid.org/0000-0002-6212-1102
Jack McGrathDepartment of Chemistry, University of Cincinnati, P.O. Box 210172, Cincinnati, OH, 45221, USA.
Rabin SiwakotiDepartment of Chemistry, University of Cincinnati, P.O. Box 210172, Cincinnati, OH, 45221, USA.
Jianbing Jimmy JiangDepartment of Chemistry, University of Cincinnati, P.O. Box 210172, Cincinnati, OH, 45221, USA. jianbing.jiang@uc.edu.ORCID http://orcid.org/0000-0002-7466-522X

Funding

National Science Foundation (NSF) CBET-2112798
6 · The paper itself

Abstract

Lithium-based nonaqueous redox flow batteries (LRFBs) are alternative systems to conventional aqueous redox flow batteries because of their higher operating voltage and theoretical energy density. However, the use of ion-selective membranes limits the large-scale applicability of LRFBs. Here, we report high-voltage membrane-free LRFBs based on an all-organic biphasic system that uses Li metal anode and 2,4,6-tri-(1-cyclohexyloxy-4-imino-2,2,6,6-tetramethylpiperidine)-1,3,5-triazine (Tri-TEMPO), N-propyl phenothiazine (C3-PTZ), and tris(dialkylamino)cyclopropenium (CP) cathodes. Under static conditions, the Li||Tri-TEMPO, Li||C3-PTZ, and Li||CP batteries with 0.5 M redox-active material deliver capacity retentions of 98%, 98%, and 92%, respectively, for 100 cycles over ~55 days at the current density of 1 mA/cm

Identifiers

PMID37553368
PMCPMC10409715

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.