ArticleACS organic & inorganic Au2023
Merging Cu(I) and Cu(II) Photocatalysis: Development of a Versatile Oxohalogenation Protocol for the Sequential Cu(II)/Cu(I)-Catalyzed Oxoallylation of Vinylarenes.
Article in ACS organic & inorganic Au, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
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Who cites it
6 citing papers in PubMed.
- Light-Driven Proton-Coupled Two-Electron Ligand Reduction Causes the Rearrangement of the Coordination Sphere in Cu(I) 4Journal of the American Chemical Society · 2026Article
- Synthesis of CJACS Au · 2026Article
- Photoexcited LMCT of CuNature communications · 2025Article
- Tuning Co-Operative Energy Transfer in Copper(I) Complexes Using Two-Photon Absorbing Diimine-Based Ligand Sensitizers.Angewandte Chemie (International ed. in English) · 2025Article
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Authors and funding
4 authors.
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Abstract
A sequential photocatalytic strategy is developed via the merger of Cu(II)/Cu(I)-catalytic cycles for the oxoallylation of vinyl arenes via α-haloketones. The initial Cu(II)-photocatalyzed oxohalogenation exploits ligand-to-metal charge transfer (LMCT) to generate halide radicals from acyl halides utilizing air as a terminal oxidant and can be employed for the late-stage modification of pharmaceuticals and agrochemicals. α-Bromoketones obtained this way can be subsequently subjected to a one-pot Cu(I)-photocatalyzed allylation. This sequential photocatalysis proceeds in a highly regio- and chemoselective fashion and is inconsequential to the electronic nature of styrenes.
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Registered trials
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