ArticleNature communications2023
Accessing five oxidation states of uranium in a retained ligand framework.
Article in Nature communications, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 13 papers.
What it found
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Who cites it
13 citing papers in PubMed, 63 citations in OpenAlex.
- Approaching cumulative quintuple bonds in all-metal uranyl analogs.National science review · 2026Article
- Resolving the innerChemical science · 2026Article
- Tuning Uranium Redox Chemistry in Asymmetric Polyoxometalate Complexes: Access to U(IV), U(V), and Transient U(VI).Inorganic chemistry · 2026Article
- Tuning reactivity at uranium through heterometal substitution in a redox-active thiomolybdate metalloligand.Chemical science · 2026Article
- High-pressure synthesis of UCommunications chemistry · 2026Article
- Multiple oxidation states of uranium stabilized by anChemical science · 2026Article
- Computational Investigation of the Chemical Bond between An(III) Ions and Soft-Donor Ligands.Inorganic chemistry · 2025Article
- Uranium(III) and Uranium(IV)Inorganic chemistry · 2025Article
- UInorganic chemistry · 2025Article
- Influence of 1,2,4-Tri-Inorganic chemistry · 2024Article
- Molecular Models of Atomically Dispersed Uranium at MoSJournal of the American Chemical Society · 2024Article
- What is the nature of the uranium(iii)-arene bond?Chemical science · 2024Article
- Solar-powered simultaneous highly efficient seawater desalination and highly specific target extraction with smart DNA hydrogels.Science advances · 2023Article
Corrections and comments
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Authors and funding
8 authors at 2 institutions in 1 country.
Funding
Abstract
Understanding and exploiting the redox properties of uranium is of great importance because uranium has a wide range of possible oxidation states and holds great potential for small molecule activation and catalysis. However, it remains challenging to stabilise both low and high-valent uranium ions in a preserved ligand environment. Herein we report the synthesis and characterisation of a series of uranium(II-VI) complexes supported by a tripodal tris(amido)arene ligand. In addition, one- or two-electron redox transformations could be achieved with these compounds. Moreover, combined experimental and theoretical studies unveiled that the ambiphilic uranium-arene interactions are the key to balance the stabilisation of low and high-valent uranium, with the anchoring arene acting as a δ acceptor or a π donor. Our results reinforce the design strategy to incorporate metal-arene interactions in stabilising multiple oxidation states, and open up new avenues to explore the redox chemistry of uranium.
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.