Fluorocarbonylation via palladium/phosphine synergistic catalysis.

Mingxin Zhao, Miao Chen, Tian Wang, Shuhan Yang, Qian Peng, Pingping Tang

Abstract read

In one paragraph

Article in Nature communications, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it

0cells of the map it votes in

1citing papers in PubMed

–field-weighted citation impact

1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

Cu single-atom embedded g-CNature communications · 2025
Article

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors.

Mingxin Zhao *State Key Laboratory and Institute of Elemento-Organic Chemistry, Nankai University, 300071, Tianjin, China.

Miao Chen *State Key Laboratory and Institute of Elemento-Organic Chemistry, Nankai University, 300071, Tianjin, China.

Tian WangState Key Laboratory and Institute of Elemento-Organic Chemistry, Nankai University, 300071, Tianjin, China.

Shuhan YangState Key Laboratory and Institute of Elemento-Organic Chemistry, Nankai University, 300071, Tianjin, China.

Qian PengState Key Laboratory and Institute of Elemento-Organic Chemistry, Nankai University, 300071, Tianjin, China. qpeng@nankai.edu.cn.ORCID http://orcid.org/0000-0002-1218-5976

Pingping TangState Key Laboratory and Institute of Elemento-Organic Chemistry, Nankai University, 300071, Tianjin, China. ptang@nankai.edu.cn.ORCID http://orcid.org/0000-0002-8296-5695

Funding

National Natural Science Foundation of China (National Science Foundation of China) 21890722National Natural Science Foundation of China (National Science Foundation of China) 21925105National Natural Science Foundation of China (National Science Foundation of China) 92156001National Natural Science Foundation of China (National Science Foundation of China) 92156017

6 · The paper itself

Abstract

Despite the growing importance of fluorinated organic compounds in pharmaceuticals, agrochemicals, and materials science, the introduction of fluorine into organic molecules is still a challenge, and no catalytic fluorocarbonylation of aryl/alkyl boron compounds has been reported to date. Herein, we present the development of palladium and phosphine synergistic redox catalysis of fluorocarbonylation of potassium aryl/alkyl trifluoroborate. Trifluoromethyl arylsulfonate (TFMS), which was used as a trifluoromethoxylation reagent, an easily handled and bench-scale reagent, has been employed as an efficient source of COF

Identifiers

PMID37524725

DOI10.1038/s41467-023-40180-6

PMCPMC10390470

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LicenceCC BY

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.