Evidence map›Paper›PMID 37514528›Full record

ArticlePolymers2023

One-Step Method for Direct Acrylation of Vegetable Oils: A Biobased Material for 3D Printing.

Cristian Mendes-Felipe, Igor Isusi, Olga Gómez-Jiménez-Aberasturi, Soraya Prieto-Fernandez, Leire Ruiz-Rubio, Marco Sangermano, José Luis Vilas-Vilela

Abstract read
In one paragraph

Article in Polymers, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.

0numbers the graph read from it
0cells of the map it votes in
4citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

4 citing papers in PubMed.

  1. Article
  2. Review
  3. Article
  4. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Cristian Mendes-FelipeBCMaterials, Basque Center for Materials, Applications and Nanostructures, UPV/EHU Science Park, 48940 Leioa, Spain.ORCID 0000-0002-0801-4103
Igor IsusiMacromolecular Chemistry Group (LABQUIMAC), Department of Physical Chemistry, Faculty of Science and Technology, University of the Basque Country (UPV/EHU), 48940 Leioa, Spain.
Olga Gómez-Jiménez-AberasturiTECNALIA, Basque Research and Technology Alliance (BRTA), Parque Tecnológico de Álava, Leonardo Da Vinci 11, 01510 Minano, Spain.
Soraya Prieto-FernandezTECNALIA, Basque Research and Technology Alliance (BRTA), Parque Tecnológico de Álava, Leonardo Da Vinci 11, 01510 Minano, Spain.ORCID 0000-0002-1921-0679
Leire Ruiz-RubioBCMaterials, Basque Center for Materials, Applications and Nanostructures, UPV/EHU Science Park, 48940 Leioa, Spain.ORCID 0000-0002-2045-008X
Marco SangermanoDepartment of Applied Science and Technology (DISAT), Politecnico di Torino, 10129 Torino, Italy.ORCID 0000-0002-8630-1802
José Luis Vilas-VilelaBCMaterials, Basque Center for Materials, Applications and Nanostructures, UPV/EHU Science Park, 48940 Leioa, Spain.

Funding

Basque Government IT1756-22Basque Government KK-2021/00082Basque Government POS-E_2021_2_0001
6 · The paper itself

Abstract

The substitution of fossil resources by alternatives derived from biomass is a reality that is taking on a growing relevance in the chemical and energy industries. In this sense, fats, oils, and their derived products have become indispensable inputs due to their broad functional attributes, stable price and sustainable character. Acrylated vegetable oils are considered to be very versatile materials for very broad applications (such as in adhesives, coatings or inks) since, in the presence of photoinitiators, they can be polymerized by means of UV-initiated free radical polymerizations. The usual process for the synthesis of acrylate vegetable oils consists in reacting epoxidized oils derivatives with acrylic acid. Here, the influence of different catalysts on the activity and selectivity of the process of acrylation of epoxidized soybean oil is studied. In addition, a novel one-step method for direct acrylation of vegetable oils is also explored. This new approach advantageously uses the original vegetable resource and eliminates intermediate reactions, thus being more environmentally efficient. This study offers a simple and low-cost option for synthesizing a biomass-derived monomer and studies the potential for the 3D printing of complex structures via digital light processing (DLP) 3D printing of the thus-obtained novel sustainable formulations.

Indexed as

3D printingbiobased polymersone-step reactionsoybean oilUV-curable

Identifiers

PMID37514528
PMCPMC10384493

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.