Evidence map›Paper›PMID 37514460›Full record

ArticlePolymers2023

The Effects of the Deacetylation of Chitin Nanowhiskers on the Performance of PCL/PLA Bio-Nanocomposites.

Ivan Kelnar, Ludmila Kaprálková, Pavel Němeček, Jiří Dybal, Rasha M Abdel-Rahman, Michaela Vyroubalová, Martina Nevoralová, A M Abdel-Mohsen

Abstract read
In one paragraph

Article in Polymers, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Review
  2. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors.

Ivan KelnarInstitute of Macromolecular Chemistry, Czech Academy of Sciences, 162 00 Prague, Czech Republic.ORCID 0000-0002-2334-3319
Ludmila KaprálkováInstitute of Macromolecular Chemistry, Czech Academy of Sciences, 162 00 Prague, Czech Republic.
Pavel NěmečekInstitute of Macromolecular Chemistry, Czech Academy of Sciences, 162 00 Prague, Czech Republic.
Jiří DybalInstitute of Macromolecular Chemistry, Czech Academy of Sciences, 162 00 Prague, Czech Republic.ORCID 0000-0002-9148-3655
Rasha M Abdel-RahmanInstitute of Macromolecular Chemistry, Czech Academy of Sciences, 162 00 Prague, Czech Republic.
Michaela VyroubalováInstitute of Macromolecular Chemistry, Czech Academy of Sciences, 162 00 Prague, Czech Republic.ORCID 0000-0002-8340-7337
Martina NevoralováInstitute of Macromolecular Chemistry, Czech Academy of Sciences, 162 00 Prague, Czech Republic.ORCID 0000-0003-2153-8611
A M Abdel-MohsenInstitute of Macromolecular Chemistry, Czech Academy of Sciences, 162 00 Prague, Czech Republic.ORCID 0000-0003-1872-9425

Funding

Ministry of Education Youth and Sports LUAUS23004
6 · The paper itself

Abstract

The multiple roles of organic nanofillers in biodegradable nanocomposites (NC) with a blend-based matrix is not yet fully understood. This work highlights combination of reinforcing and structure-directing effects of chitin nanowhiskers (CNW) with different degrees of deacetylation (DA), i.e., content of primary or secondary amines on their surface, in the nanocomposite with the PCL/PLA 1:1 matrix. Of importance is the fact that aminolysis with CNW leading to chain scission of both polyesters, especially of PLA, is practically independent of DA. DA also does not influence thermal stability. At the same time, the more marked chain scission/CNW grafting for PLA in comparison to PCL, causing changes in rheological parameters of components and related structural alterations, has crucial effects on mechanical properties in systems with a bicontinuous structure. Favourable combinations of multiple effects of CNW leads to enhanced mechanical performance at low 1% content only, whereas negative effects of structural changes, particularly of changed continuity, may eliminate the reinforcing effects of CNW at higher contents. The explanation of both synergistic and antagonistic effects of structures formed is based on the correspondence of experimental results with respective basic model calculations.

Indexed as

chitin nanowhiskersdeacetylationdynamic asymmetrypoly(lactic acid)poly(ε-caprolactone)

Identifiers

PMID37514460
PMCPMC10384066

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.