Evidence map›Paper›PMID 37513382›Full record

ArticleMolecules (Basel, Switzerland)2023

Resonant Inner-Shell Photofragmentation of Adamantane (C10H16).

Smita Ganguly, Mathieu Gisselbrecht, Per Eng-Johnsson, Raimund Feifel, Sergio Díaz-Tendero, Eva Muchová, Aleksandar R Milosavljević, Patrick Rousseau, Sylvain Maclot

Abstract read
In one paragraph

Article in Molecules (Basel, Switzerland), 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors.

Smita GangulyDepartment of Physics, Lund University, 22100 Lund, Sweden.ORCID 0000-0002-4988-4658
Mathieu GisselbrechtDepartment of Physics, Lund University, 22100 Lund, Sweden.ORCID 0000-0003-0257-7607
Per Eng-JohnssonDepartment of Physics, Lund University, 22100 Lund, Sweden.ORCID 0000-0003-2135-0248
Raimund FeifelDepartment of Physics, University of Gothenburg, Origovagen 6 B, 41296 Gothenburg, Sweden.ORCID 0000-0001-5234-3935
Sergio Díaz-TenderoDepartment of Chemistry, Universidad Autonoma de Madrid, 28049 Madrid, Spain.ORCID 0000-0001-6253-6343
Eva MuchováDepartment of Physical Chemistry, University of Chemistry and Technology, Technická 5, 166 28 Prague, Czech Republic.ORCID 0000-0002-3768-6208
Aleksandar R MilosavljevićSynchrotron SOLEIL, L'Orme de Merisiers, Saint Aubin, BP48, 91192 Gif-sur-Yvette CEDEX, France.ORCID 0000-0003-3541-8872
Patrick RousseauNormandie University, ENSICAEN, UNICAEN, CEA, CNRS, CIMAP, 14000 Caen, France.ORCID 0000-0001-7217-2707
Sylvain MaclotDepartment of Physics, University of Gothenburg, Origovagen 6 B, 41296 Gothenburg, Sweden.ORCID 0000-0001-5587-7182

Funding

CALIPSOplus 730872Czech Science Foundation 21-26601XEuropean Cooperation in Science and Technology CA18212Helmholtz Foundation HIRS-0018Spanish Ministry of Science and Innovation CEX2018-000805-MSpanish Ministry of Science and Innovation PID2019-110091GB-I00Swedish Research Council VR2020-0520
6 · The paper itself

Abstract

Adamantane, the smallest diamondoid molecule with a symmetrical cage, contains two distinct carbon sites, CH and CH2. The ionization/excitation of the molecule leads to the cage opening and strong structural reorganization. While theoretical predictions suggest that the carbon site CH primarily causes the cage opening, the role of the other CH2 site remains unclear. In this study, we used advanced experimental Auger electron-ion coincidence techniques and theoretical calculations to investigate the fragmentation dynamics of adamantane after resonant inner-shell photoexcitation. Our results demonstrate that some fragmentation channels exhibit site-sensitivity of the initial core-hole location, indicating that different carbon site excitations could lead to unique cage opening mechanisms.

Indexed as

adamantaneAE–PICO/PIPICO coincidenceinner-shell fragmentationsite-selectivity

Identifiers

PMID37513382
PMCPMC10384773

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.