Evidence map›Paper›PMID 37500623›Full record

ArticleNature communications2023

Tuning the zeolite acidity enables selectivity control by suppressing ketene formation in lignin catalytic pyrolysis.

Zeyou Pan, Allen Puente-Urbina, Syeda Rabia Batool, Andras Bodi, Xiangkun Wu, Zihao Zhang, Jeroen A van Bokhoven, Patrick Hemberger

Open access · goldAbstract read
In one paragraph

Article in Nature communications, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.

0numbers the graph read from it
0cells of the map it votes in
5citing papers in PubMed
4.9field-weighted citation impact, top 4% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

5 citing papers in PubMed, 45 citations in OpenAlex.

  1. Article
  2. Article
  3. Facile Decarbonylation Suppresses theThe Journal of organic chemistry · 2025
    Article
  4. Article
  5. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors at 3 institutions in 2 countries.

Zeyou PanPaul Scherrer Institute, Forschungsstrasse 111, CH-5232, Villigen PSI, Switzerland.ORCID http://orcid.org/0000-0002-2502-9454
Allen Puente-UrbinaInstitute for Chemical and Bioengineering, Department of Chemistry and Applied Biosciences, ETH Zurich, 8093, Zurich, Switzerland.ORCID http://orcid.org/0000-0001-5328-2142
Syeda Rabia BatoolInstitute for Chemical and Bioengineering, Department of Chemistry and Applied Biosciences, ETH Zurich, 8093, Zurich, Switzerland.
Andras BodiPaul Scherrer Institute, Forschungsstrasse 111, CH-5232, Villigen PSI, Switzerland.ORCID http://orcid.org/0000-0003-2742-1051
Xiangkun WuPaul Scherrer Institute, Forschungsstrasse 111, CH-5232, Villigen PSI, Switzerland.
Zihao ZhangPaul Scherrer Institute, Forschungsstrasse 111, CH-5232, Villigen PSI, Switzerland.
Jeroen A van BokhovenPaul Scherrer Institute, Forschungsstrasse 111, CH-5232, Villigen PSI, Switzerland. jeroen.vanbokhoven@chem.ethz.ch.ORCID http://orcid.org/0000-0002-4166-2284
Patrick HembergerPaul Scherrer Institute, Forschungsstrasse 111, CH-5232, Villigen PSI, Switzerland. patrick.hemberger@psi.ch.ORCID http://orcid.org/0000-0002-1251-4549
Paul Scherrer Institute · CHETH Zurich · CHNational Laboratory of the Rockies · US

Funding

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung (Swiss National Science Foundation) 200021_178952
6 · The paper itself

Abstract

Unveiling catalytic mechanisms at a molecular level aids rational catalyst design and selectivity control for process optimization. In this study, we find that the Brønsted acid site density of the zeolite catalyst efficiently controls the guaiacol catalytic pyrolysis mechanism. Guaiacol demethylation to catechol initiates the reaction, as evidenced by the detected methyl radicals. The mechanism branches to form either fulvenone (c-C

Identifiers

PMID37500623
PMCPMC10374901
OpenAlexW4385297609

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.