ArticleScientific reports2023
Effects of functionalization and silane modification of hexagonal boron nitride on thermal/mechanical/morphological properties of silicon rubber nanocomposite.
Article in Scientific reports, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
3 citing papers in PubMed, 28 citations in OpenAlex.
- Article
- Silicone Composites with Electrically Oriented Boron Nitride Platelets and Carbon Microfibers for Thermal Management of Electronics.Polymers · 2025Article
- Synergistic Effect of Aluminum Nitride and Carbon Nanotube-Reinforced Silicon Rubber Nanocomposites.Molecules (Basel, Switzerland) · 2024Article
Corrections and comments
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Authors and funding
3 authors at 2 institutions in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Hexagonal boron nitride (h-BN) nanoparticles could induce interesting properties to silicone rubber (SR) but, the weak filler-matrix interfacial interaction causes agglomeration of the nanoparticles and declines the performance of the nanocomposite. In this work, h-BN nanoparticles were surface modified using vinyltrimethoxysilane (VTMS) at different concentrations. Before silane modification, h-BN nanoparticles were hydroxylated using 5 molar sodium hydroxide. The nanoparticles were characterized to assess success of silane grafting. The pure and modified h-BN nanoparticles were applied at 1, 3 and 5 wt% to HTV silicon rubber (SR). The curing, thermal, mechanical and morphological properties and hydrophobicity of the nanocomposites were evaluated. The morphology of the SR nanocomposites was characterized using AFM and FE-SEM analysis. It was found that silane grafting on the h-BN nanoparticles improves crosslink density but declines curing rate index (CRI) of the SR nanocomposite (at 5 wt% loading content) by 0.7 (dN m) and 3.5%, respectively. It also increased water contact angle of the nanocomposites from 97.5° to 107°. The improved nanoparticle-rubber interfacial interactions caused better dispersion of h-BN nanoparticles in SR matrix (at 5 wt%) that enhanced the elongation at break, modulus at 300% and Tg of the SR nanocomposites.
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Registered trials
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