Evidence map›Paper›PMID 37482883›Full record

ArticlePhysical chemistry chemical physics : PCCP2023

Revisiting the origin of the bending in group 2 metallocenes AeCp

Tetiana Sergeieva, T Ilgin Demirer, Axel Wuttke, Ricardo A Mata, André Schäfer, Gerrit-Jan Linker, Diego M Andrada

Abstract read
In one paragraph

Article in Physical chemistry chemical physics : PCCP, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. A Borane Sandwich Analogue of Ferrocene.Angewandte Chemie (International ed. in English) · 2026
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Tetiana SergeievaDepartment of Chemistry, Saarland University, Campus Saarbrücken, 66123 Saarbrücken, Germany. diego.andrada@uni-saarland.de.
T Ilgin DemirerDepartment of Chemistry, Saarland University, Campus Saarbrücken, 66123 Saarbrücken, Germany. diego.andrada@uni-saarland.de.
Axel WuttkeInstitute for Physical Chemistry, Georg-August-University Göttingen, Tammannstrasse 6, D-37077 Göttingen, Germany. ricardo.mata@chemie.uni-goettingen.de.
Ricardo A MataInstitute for Physical Chemistry, Georg-August-University Göttingen, Tammannstrasse 6, D-37077 Göttingen, Germany. ricardo.mata@chemie.uni-goettingen.de.ORCID http://orcid.org/0000-0002-2720-3364
André SchäferDepartment of Chemistry, Saarland University, Campus Saarbrücken, 66123 Saarbrücken, Germany. diego.andrada@uni-saarland.de.ORCID http://orcid.org/0000-0002-5969-6618
Gerrit-Jan LinkerMESA+ Institute for Nanotechnology, University of Twente, 7522 NB Enschede, The Netherlands. g.linker@utwente.nl.
Diego M AndradaDepartment of Chemistry, Saarland University, Campus Saarbrücken, 66123 Saarbrücken, Germany. diego.andrada@uni-saarland.de.ORCID http://orcid.org/0000-0003-2515-7859

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Metallocenes are well-established compounds in organometallic chemistry, and can exhibit either a coplanar structure or a bent structure according to the nature of the metal center (E) and the cyclopentadienyl ligands (Cp). Herein, we re-examine the chemical bonding to underline the origins of the geometry and stability observed experimentally. To this end, we have analysed a series of group 2 metallocenes [Ae(C

Identifiers

PMID37482883
PMCPMC10395002

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.