Evidence map›Paper›PMID 37482556›Full record

ArticleNature communications2023

Diversity-oriented synthesis of P-stereogenic and axially chiral monodentate biaryl phosphines enabled by C-P bond cleavage.

Liangzhi Pang, Zhan Huang, Qilin Sun, Gen Li, Jiaojiao Liu, Baoli Li, Congyue Ma, Jiaxu Guo, Chuanzhi Yao, Jie Yu and 1 more

Abstract read
In one paragraph

Article in Nature communications, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

11 authors.

Liangzhi PangDepartment of Applied Chemistry, Anhui Agricultural University, 230036, Hefei, China.
Zhan HuangDepartment of Applied Chemistry, Anhui Agricultural University, 230036, Hefei, China.
Qilin SunDepartment of Applied Chemistry, Anhui Agricultural University, 230036, Hefei, China.
Gen LiDepartment of Applied Chemistry, Anhui Agricultural University, 230036, Hefei, China.
Jiaojiao LiuDepartment of Applied Chemistry, Anhui Agricultural University, 230036, Hefei, China.
Baoli LiDepartment of Applied Chemistry, Anhui Agricultural University, 230036, Hefei, China.
Congyue MaDepartment of Applied Chemistry, Anhui Agricultural University, 230036, Hefei, China.
Jiaxu GuoDepartment of Applied Chemistry, Anhui Agricultural University, 230036, Hefei, China.
Chuanzhi YaoDepartment of Applied Chemistry, Anhui Agricultural University, 230036, Hefei, China.
Jie YuDepartment of Applied Chemistry, Anhui Agricultural University, 230036, Hefei, China. jieyu@ustc.edu.cn.ORCID http://orcid.org/0000-0002-9968-1429
Qiankun LiDepartment of Applied Chemistry, Anhui Agricultural University, 230036, Hefei, China. liqk@ahau.edu.cn.ORCID http://orcid.org/0000-0002-4826-1926

Funding

National Natural Science Foundation of China (National Science Foundation of China) 22001008National Natural Science Foundation of China (National Science Foundation of China) 22201009National Natural Science Foundation of China (National Science Foundation of China) 92156022Natural Science Foundation of Anhui Province (Anhui Provincial Natural Science Foundation) 1908085QB79
6 · The paper itself

Abstract

Chiral monodentate biaryl phosphines (MOPs) have attracted intense attention as chiral ligands over the past decades. However, the creation of structurally diverse chiral MOPs with both P- and axial chirality is still in high demand but challenging. Here, we show a distinct strategy for diversity-oriented synthesis of structurally diverse MOPs containing both P- and axial chirality enabled by enantioselective C-P bond cleavage. The key chiral Pd

Identifiers

PMID37482556
PMCPMC10363526

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.