Evidence map›Paper›PMID 37476723›Full record

ArticleChemical science2023

A path towards single molecule vibrational strong coupling in a Fabry-Pérot microcavity.

Arghadip Koner, Matthew Du, Sindhana Pannir-Sivajothi, Randall H Goldsmith, Joel Yuen-Zhou

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Chemical science, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Article
  2. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors.

Arghadip KonerDepartment of Chemistry and Biochemistry, University of California San Diego La Jolla California 92093 USA joelyuen@ucsd.edu.
Matthew DuDepartment of Chemistry, University of Chicago 5735 S Ellis Ave Chicago Illinois 60637 USA.
Sindhana Pannir-SivajothiDepartment of Chemistry and Biochemistry, University of California San Diego La Jolla California 92093 USA joelyuen@ucsd.edu.
Randall H GoldsmithDepartment of Chemistry, University of Wisconsin-Madison Madison Wisconsin 53706-1322 USA.ORCID https://orcid.org/0000-0001-9083-8592
Joel Yuen-ZhouDepartment of Chemistry and Biochemistry, University of California San Diego La Jolla California 92093 USA joelyuen@ucsd.edu.ORCID https://orcid.org/0000-0002-8605-9665

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Interaction between light and molecular vibrations leads to hybrid light-matter states called vibrational polaritons. Even though many intriguing phenomena have been predicted for single-molecule vibrational strong coupling (VSC), several studies suggest that these effects tend to be diminished in the many-molecule regime due to the presence of dark states. Achieving single or few-molecule vibrational polaritons has been constrained by the need for fabricating extremely small mode volume infrared cavities. In this theoretical work, we propose an alternative strategy to achieve single-molecule VSC in a cavity-enhanced Raman spectroscopy (CERS) setup, based on the physics of cavity optomechanics. We then present a scheme harnessing few-molecule VSC to thermodynamically couple two reactions, such that a spontaneous electron transfer can now fuel a thermodynamically uphill reaction that was non-spontaneous outside the cavity.

Identifiers

PMID37476723
PMCPMC10355109

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.