ArticleNature communications2023
Actinide inverse trans influence versus cooperative pushing from below and multi-center bonding.
Article in Nature communications, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
8 citing papers in PubMed.
- Oxidation State Dependence of the Actinide MInorganic chemistry · 2026Article
- A lanthanide-carbon triple bond stabilized within a fullerene cage.Nature chemistry · 2025Article
- Uranium-stibinidiide, -stibinidene, and -stibido multiple bonds and uranium-nitride formation from multimetallic diuranium-distibene-mediated dinitrogen cleavage.Nature communications · 2025Article
- Insights into Structural Diversity and Morphotropic Evolution in AChemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- f-Element Zintl Chemistry: Actinide-Mediated Dehydrocoupling of HInorganic chemistry · 2024Article
- Progress in Nonaqueous Molecular Uranium Chemistry: Where to Next?Inorganic chemistry · 2024Article
- Thorium(IV)-antimony complexes exhibiting single, double, and triple polar covalent metal-metal bonds.Nature chemistry · 2024Article
- 10-Valence-Electron C≡O and the 14-VE C≡Pt: Two Triple-Bonded Isoelectronic Families Differing by aInorganic chemistry · 2023Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
2 authors.
Funding
Abstract
Actinide-ligand bonds with high multiplicities remain poorly understood. Decades ago, an effect known as 6p pushing from below (PFB) was proposed to enhance actinide covalency. A related effect-also poorly understood-is inverse trans influence (ITI). The present computational study of actinide-ligand covalent interactions with high bond multiplicities quantifies the energetic contributions from PFB and identifies a hitherto overlooked fourth bonding interaction for 2nd-row ligands in the studied organometallic systems. The latter are best described by a terminal O/N ligand exhibiting quadruple bonding interactions with the actinide. The 4th interaction may be characterized as a multi-center or charge-shift bond involving the trans ligand. It is shown in this work that the 4th bonding interaction is a manifestation of ITI, assisted by PFB, and provides a long-sought missing piece in the understanding of actinide chemistry.
Identifiers
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Registered trials
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