Tetrathiafulvalene-2,3,6,7-tetrathiolate linker redox-state elucidation

Ningxin Jiang, Jan-Niklas Boyn, Arun Ramanathan, Henry S La Pierre, John S Anderson

Abstract read

In one paragraph

Article in Chemical communications (Cambridge, England), 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it

0cells of the map it votes in

1citing papers in PubMed

–field-weighted citation impact

1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

Pre-synthetic redox control of structure and properties in copper TTFtt coordination polymers.Chemical science · 2025
Article

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors.

Ningxin JiangDepartment of Chemistry and The James Franck Institute, University of Chicago, Chicago, Illinois, 60637, USA. jsanderson@uchicago.edu.

Jan-Niklas BoynDepartment of Mechanical and Aerospace Engineering, Princeton University, Princeton, New Jersey, 08544-5263, USA.ORCID http://orcid.org/0000-0002-6240-3759

Arun RamanathanSchool of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, Georgia, 30332-0400, USA. hsl@gatech.edu.ORCID http://orcid.org/0000-0002-1787-7058

Henry S La PierreSchool of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, Georgia, 30332-0400, USA. hsl@gatech.edu.ORCID http://orcid.org/0000-0002-0895-0655

John S AndersonDepartment of Chemistry and The James Franck Institute, University of Chicago, Chicago, Illinois, 60637, USA. jsanderson@uchicago.edu.ORCID http://orcid.org/0000-0002-0730-3018

Funding

X-ray Absorption Spectroscopy (XAS) pp.711-759P41GM103393 · NIGMS · STANFORD UNIVERSITY · PI HODGSON, KEITH O · 2012 to 2019

$30.6M

NIGMS NIH HHS P41 GM103393

6 · The paper itself

Abstract

Sulfur K-edge XAS data provide a unique tool to examine oxidation states and covalency in electronically complex S-based ligands. We present sulfur K-edge X-ray absorption spectroscopy on a discrete redox-series of Ni-based tetrathiafulvalene tetrathiolate (TTFtt) complexes as well as on a 1D coordination polymer (CP), NiTTFtt. Experiment and theory suggest that Ni-S covalency decreases with oxidation which has implications for charge transport pathways.

Identifiers

PMID37458323

DOI10.1039/d3cc02325g

PMCPMC10392963

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.