Evidence map›Paper›PMID 37446778›Full record

ArticleMolecules (Basel, Switzerland)2023

Engineering Two-Dimensional Multilevel Supramolecular Assemblies from a Bifunctional Ligand on Au(111).

Rongyu Tang, Yang Song, Lizhi Zhang, Ziliang Shi

Abstract read
In one paragraph

Article in Molecules (Basel, Switzerland), 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors.

Rongyu TangCenter for Soft Condensed Matter Physics and Interdisciplinary Research, School of Physical Science and Technology, Soochow University, Suzhou 215006, China.
Yang SongLaboratory of Theoretical and Computational Nanoscience, National Center for Nanoscience and Technology, Beijing 100190, China.
Lizhi ZhangLaboratory of Theoretical and Computational Nanoscience, National Center for Nanoscience and Technology, Beijing 100190, China.
Ziliang ShiCenter for Soft Condensed Matter Physics and Interdisciplinary Research, School of Physical Science and Technology, Soochow University, Suzhou 215006, China.ORCID 0000-0002-3865-0098

Funding

National Natural Science Foundation of China 21972101
6 · The paper itself

Abstract

Herein, we demonstrate the supramolecular assemblies from a bifunctional ligand on Au(111), towards engineering two-dimensional (metal-) organic multilevel nanostructures. The bifunctional ligand employed, including two Br atoms and one carboxylic terminal, offers multiple bonding motifs with different configurations and binding energies. These bonding motifs are highly self-selective and self-recognizable, and thus afford the formation of subunits that contribute to engineering multilevel self-assemblies. Our scanning tunneling microscopy experiments, in combination with the density functional theory calculations, revealed various hydrogen, halogen and alkali-carboxylate bonding motifs dictating the different levels of the assemblies. The multilevel assembly protocol based on a judicious choice of multiple bonding motifs guarantees a deliberate control of surface-confined (metal-) organic nanostructures. Our findings may present new opportunities for the fabrication of complex two-dimensional (metal-) organic nanostructures with potential in applications of functionally diverse nanomaterials.

Indexed as

MetalsNanostructuresEngineeringLigandsSurface PropertiesLigandsMetalsdensity functional theorymetal-organic coordinationscanning tunneling microscopysurfacetwo-dimensional supramolecular self-assembly

Identifiers

PMID37446778
PMCPMC10343213

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.