ArticleNanomaterials (Basel, Switzerland)2023
Electrochemical Mechanism of Oxidative Dissolution of Silver Nanoparticles in Water: Effect of Size on Electrode Potential and Solubility.
Article in Nanomaterials (Basel, Switzerland), 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
7 citing papers in PubMed, 17 citations in OpenAlex.
- Physicochemical characterization and optimization of Tulsi-mediated silver nanocomposites with enhanced insecticidal activity againstRSC advances · 2026Article
- A Highly Sensitive Electrochemical Immunosensor Based on Core-Shell SiOFoods (Basel, Switzerland) · 2026Article
- Fabrication of Highly Conductive Inkjet Printing Silver Nanoparticle Ink via a Synergistic Strategy Combining Centrifugal Classification and Dispersant Optimization.Materials (Basel, Switzerland) · 2026Article
- Silver Nanoparticles and Antibiotics: A Promising Synergistic Approach to Multidrug-Resistant Infections.Microorganisms · 2025Review
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- Synergistic effect of Silver-Nanodiamond composite as an efficient antibacterial agent againstHeliyon · 2024Article
Corrections and comments
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Authors and funding
2 authors at 1 institution in 1 country.
Funding
Abstract
For the first time, an electrochemical mechanism of oxidative dissolution of silver nanoparticles in aqueous solutions is suggested and substantiated. The dissolution is caused by the occurrence of two interrelated electrochemical processes: (1) silver oxidation on a microanode and (2) oxygen reduction on a microcathode. According to the suggested model, the standard electrode potential of a nanoparticle decreases with a decrease in its size, which leads to an increase in the electromotive force of the oxidative dissolution of silver. A proportional dependence of the solubility of nanoparticles on their standard potential is revealed. An empirical equation is derived that relates the solubility of AgNPs to their electrode potential and size. In the course of oxidation, silver nanoparticles undergo aggregation with a gradual increase in the potential to the value characteristic of the bulk metal. This leads to the deceleration and practical cessation of the dissolution.
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Registered trials
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