ArticleInternational journal of molecular sciences2023
Dynamics in Quaternary Ionic Liquids with Non-Flexible Anions: Insights from Mechanical Spectroscopy.
Article in International journal of molecular sciences, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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Who cites it
3 citing papers in PubMed.
- Pyrrolidinium and Imidazolium-Based Ionic Liquids as Electrolytes for NaThe journal of physical chemistry. B · 2026Article
- Aprotic Electrolytes Beyond Organic Carbonates: Transport Properties of LiTFSI Solutions in S-Based Solvents.ChemSusChem · 2025Article
- Structural Properties of [N1888][TFSI] Ionic Liquid: A Small Angle Neutron Scattering and Polarizable Molecular Dynamics Study.The journal of physical chemistry. B · 2024Article
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Authors and funding
5 authors.
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Abstract
The present work investigates how mechanical properties and ion dynamics in ionic liquids (ILs) can be affected by ILs' design while considering possible relationships between different mechanical and transport properties. Specifically, we study mechanical properties of quaternary ionic liquids with rigid anions by means of Dynamical Mechanical Analysis (DMA). We are able to relate the DMA results to the rheological and transport properties provided by viscosity, conductivity, and diffusion coefficient measurements. A good agreement is found in the temperature dependence of different variables described by the Vogel-Fulcher-Tammann model. In particular, the mechanical spectra of all the measured liquids showed the occurrence of a relaxation, for which the analysis suggested its attribution to a diffusive process, which becomes evident when the ion dynamics are not affected by the fast structural reorganization of flexible anions on a local level.
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