ArticleMaterials (Basel, Switzerland)2023
Eco-Friendly Approach for the Construction of Superhydrophobic Coating on Stainless Steel Metal Based on Biological Metal-Organic Framework and Its Corrosion Resistance Performance.
Article in Materials (Basel, Switzerland), 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
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5 citing papers in PubMed, 13 citations in OpenAlex.
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- New approach for processing chitosan as low cost protective hybrid coating for C-steel in acid media.Heliyon · 2024Article
- An eco-friendly and facile method for oil-water separation using the bio-Zn oxide-based superhydrophobic membrane.Water science and technology : a journal of the International Association on Water Pollution Research · 2024Article
- Article
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Authors and funding
3 authors at 3 institutions in 2 countries.
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No grant is acknowledged in the PubMed record.
Abstract
In this paper, we present a sustainable approach for the creation of superhydrophobic (SP) coating on a stainless-steel substrate based on a biological metal-organic framework (MOF). The MOF was synthesized using aspartic acid as a linker and copper ions as a core metal. Two SP coatings were well constructed on stainless steel utilizing electrodeposition of nickel (Ni) and nickel altered by MOF (Ni@Bio-MOF) coatings followed by soaking in a solution of stearic acid in ethanol. The results of Fourier transform infrared spectroscopy demonstrate that the stearic acid-grafted nickel coating (Ni@SA) and the stearic acid-grafted Ni@Bio-MOF composite (Ni@Bio-MOF@SA), were effectively deposited on the stainless steel. The wettability findings displayed that the water contact angle of Ni@SA and Ni@Cu-As MOF@SA are 160° ± 1.1°, and 168° ± 1.2°, respectively. The prepared SP coating was also found to be chemically and mechanically stable. The results show that the Ni@SA coating maintains SP characteristics in a pH range of 3-11 while the Ni@Cu-As MOF@SA coating retained SP characteristics in a pH range of 1-13. Additionally, the superhydrophobic Ni@SA coating demonstrated SP characteristics up to a length of abrasion equal to 1300 mm, while the Ni@Cu-As MOF@SA coating exhibited SP characteristics up to a length of abrasion equal to 2700 mm. Furthermore, the Ni@SA and Ni@Cu-As MOF@SA coatings exhibited significantly improved corrosion protection in a 0.5 M NaCl solution compared with bare stainless steel, with protection efficiencies of approximately 94% and 99%, respectively. The results of this study demonstrate that the proposed approach is a promising method for the fabrication of eco-friendly and corrosion-resistant SP coatings on stainless steel substrate.
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