ArticleNature communications2023
Construction of room temperature phosphorescent materials with ultralong lifetime by in-situ derivation strategy.
Article in Nature communications, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 12 papers.
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Who cites it
12 citing papers in PubMed.
- Visible-Light-Activated Multi-Color Room Temperature Phosphorescence Under Extreme Aqueous Environment and High Temperature via Supramolecular Assembly.Small (Weinheim an der Bergstrasse, Germany) · 2026Article
- Rational Design and Development of Organic Afterglow Nanoparticles for Image-Guided Interventions.Small methods · 2026Review
- Rigid ionic-bonding networks boosting organic room temperature phosphorescence.Nature communications · 2026Article
- Observation of thermally activated intersystem crossing in room-temperature phosphorescence of weakly donor-acceptor-donor π-ternary molecules.Chemical science · 2026Article
- Visible-Light-Activated Multi-Color Tunable Time-Dependent Afterglow Triggered by Variable Conjugation Effects via the Transformation of Matrix.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Achieving Highly Robust Polymeric Microspheres with Efficient and Full-Color Organic Afterglow for 3D Printing and Anti-Counterfeiting.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Ultrasound-responsive phosphorescence in aqueous solution enabled by microscale rigid framework engineering of carbon nanodots.Light, science & applications · 2025Article
- White light-excited organic room-temperature phosphorescence for improved in vivo bioimaging.Nature communications · 2025Article
- Luminescence Properties of Hoechst 33258 in Polyvinyl Alcohol Films.International journal of molecular sciences · 2025Article
- Stepwise Stiffening Chromophore Strategy Realizes a Series of Ultralong Blue Room-Temperature Phosphorescent Materials.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- Urea-formaldehyde resin room temperature phosphorescent material with ultra-long afterglow and adjustable phosphorescence performance.Nature communications · 2024Article
- Finely manipulating room temperature phosphorescence by dynamic lanthanide coordination toward multi-level information security.Nature communications · 2024Article
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Authors and funding
9 authors.
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Abstract
Although room temperature phosphorescence (RTP) materials have been widely investigated, it is still a great challenge to improve the performance of RTP materials by promoting triplet exciton generation and stabilization. In this study, an in-situ derivation strategy was proposed to construct efficient RTP materials by in-situ deriving guest molecules and forming a rigid matrix during co-pyrolysis of guest molecules and urea. Characterizations and theoretical calculations revealed that the generated derivatives were beneficial for promoting intersystem crossing (ISC) to produce more triplet excitons, while rigid matrix could effectively suppress the non-radiative transition of triplet excitons. Thus, the in-situ derivation strategy was concluded to simultaneously promote the generation and stabilization of triplet excitons. With this method, the ultralong lifetime of RTP materials could reach up to 5.33 s and polychromatic RTP materials were easily achieved. Moreover, the potential applications of the RTP materials in reprocessing or editable anti-counterfeiting were successfully demonstrated.
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