ArticleNature communications2023
Slab gliding, a hidden factor that induces irreversibility and redox asymmetry of lithium-rich layered oxide cathodes.
Article in Nature communications, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
What it found
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Who cites it
9 citing papers in PubMed.
- Fast formation to reinforce lithium-rich cathodes.Nature · 2026Article
- Approaching Zero Voltage Attenuation of Lithium-Rich Cathodes through Electrochemical Relaxation.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Enhanced Oxygen Redox Activity and Structure Stability of P2-Type Manganese-Based Cathodes Through Medium-Entropy Strategy.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Low-Temperature Defect Healing in the Layered Zintl Phase LiInorganic chemistry · 2026Article
- Recovery of High-Voltage Oxygen Redox Activity by Eliminating Residual Oxygen Dimers.Journal of the American Chemical Society · 2025Article
- Transition Metal Slab Gliding: One Key Process for Activating Anionic Redox Reaction in P2-Type Transition Metal Oxide Cathodes.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Role of grain-level chemo-mechanics in composite cathode degradation of solid-state lithium batteries.Nature communications · 2024Article
- Electrochemomechanical failure in layered oxide cathodes caused by rotational stacking faults.Nature materials · 2024Article
- Highly reversible transition metal migration in superstructure-free Li-rich oxide boosting voltage stability and redox symmetry.Nature communications · 2024Article
Corrections and comments
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Authors and funding
13 authors.
Funding
Abstract
Lithium-rich layered oxides, despite their potential as high-energy-density cathode materials, are impeded by electrochemical performance deterioration upon anionic redox. Although this deterioration is believed to primarily result from structural disordering, our understanding of how it is triggered and/or occurs remains incomplete. Herein, we propose a theoretical picture that clarifies the irreversible transformation and redox asymmetry of lithium-rich layered oxides by introducing a series of global and local dynamic structural evolution processes involving slab gliding and transition-metal migration. We show that slab gliding plays a key role in trigger/initiating the structural disordering and consequent degradation of the anionic redox reaction. We further reveal that the 'concerted disordering mechanism' of slab gliding and transition-metal migration produces spontaneously irreversible/asymmetric lithiation and de-lithiation pathways, causing irreversible structural deterioration and the asymmetry of the anionic redox reaction. Our findings suggest slab gliding as a crucial, yet underexplored, method for achieving a reversible anionic redox reaction.
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Registered trials
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