ReviewChemical reviews2023
Insights into Single-Electron-Transfer Processes in Frustrated Lewis Pair Chemistry and Related Donor-Acceptor Systems in Main Group Chemistry.
Review in Chemical reviews, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 23 papers.
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Who cites it
23 citing papers in PubMed.
- Doping by degradation.Nature materials · 2026Article
- From [NHC─H]Angewandte Chemie (International ed. in English) · 2026Article
- Article
- Thiol-Free Sulfenylation Redefined: A Single-Atom Transfer Pathway to Symmetrical Di(hetero)arylthioethers via B(CJournal of the American Chemical Society · 2026Article
- Recent Advances in Heterogeneous Frustrated Lewis Pair: Synthesis, Characterization, and Catalysis.Advanced materials (Deerfield Beach, Fla.) · 2025Review
- Synthesis of zwitterionic open-shell bilayer spironanographenes.Nature chemistry · 2025Article
- Radical Formation by Direct Single Electron Transfer between Nitrobenzene and Anionic Organo Bases.ACS omega · 2025Article
- Hexaphenyl-1,2-Diphosphonium Dication [PhJournal of the American Chemical Society · 2025Article
- Exploring Supramolecular Frustrated Lewis Pairs.ChemPlusChem · 2025Review
- Iodoarene Activation: Take a Leap Forward toward Green and Sustainable Transformations.Chemical reviews · 2025Review
- Visible-Light-Mediated Synthesis of AnomericMolecules (Basel, Switzerland) · 2025Article
- Heterogeneous Frustrated Lewis Pair Catalysts: Rational Structure Design and Mechanistic Elucidation Based on Intrinsic Properties of Supports.Accounts of chemical research · 2025Article
- B(CChemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Article
- Synthesis and Photochemical Uncaging of Alkene-Protected, Polymer-Bound Vicinal Frustrated Lewis Pairs.Journal of the American Chemical Society · 2024Article
- Mechanistic studies on single-electron transfer in frustrated Lewis pairs and its application to main-group chemistry.Chemical Society reviews · 2024Review
- Shining light on tryptamine-derived isocyanides: access to constrained spirocylic scaffolds.Chemical science · 2024Article
- Photoinduced Site-Selective Aryl C-H Borylation with Electron-Donor-Acceptor Complex Derived from BMolecules (Basel, Switzerland) · 2024Article
- Single electron reduction of NHC-COChemical science · 2024Article
- A review of frustrated Lewis pair enabled monoselective C-F bond activation.Chemical science · 2024Review
Corrections and comments
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Authors and funding
5 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The activation and utilization of substrates mediated by Frustrated Lewis Pairs (FLPs) was initially believed to occur solely via a two-electron, cooperative mechanism. More recently, the occurrence of a single-electron transfer (SET) from the Lewis base to the Lewis acid was observed, indicating that mechanisms that proceed via one-electron-transfer processes are also feasible. As such, SET in FLP systems leads to the formation of radical ion pairs, which have recently been more frequently observed. In this review, we aim to discuss the seminal findings regarding the recently established insights into the SET processes in FLP chemistry as well as highlight examples of this radical formation process. In addition, applications of reported main group radicals will also be reviewed and discussed in the context of the understanding of SET processes in FLP systems.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.