ArticleChemical science2023
Toroidal moment and dynamical control in luminescent 1D and 3D terbium calixarene compounds.
Article in Chemical science, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
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1 citing paper in PubMed.
- Homochiral toroidal spin state in Dy(III)-based single-molecule toroics.Nature chemistry · 2026Article
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7 authors.
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Abstract
A toroidal moment can be generated spontaneously in inorganic (atom-based) ferrotoroidic materials that breaks both time-reversal and space-inversion symmetries, attracting great attention in solid-state chemistry and physics. In the field of molecular magnetism, it can also be achieved in lanthanide (Ln) involved metal-organic complexes usually with a wheel-shaped topological structure. Such complexes are called single-molecule toroics (SMTs), presenting unique advantages in spin chirality qubits and magnetoelectric coupling. However, to date, the synthetic strategies of SMTs have remained elusive, and the covalently bonded three-dimensional (3D) extended SMT has not hitherto been synthesized. Here, two luminescent Tb(iii)-calixarene aggregates with architectures of 1D chain (1) and 3D network (2) both containing the square Tb
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