ArticleAngewandte Chemie (International ed. in English)2023
Iron-Catalyzed Reductive Cross-Coupling of Alkyl Electrophiles with Olefins.
Article in Angewandte Chemie (International ed. in English), 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
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Who cites it
8 citing papers in PubMed.
- Diastereodivergent Hydroamidation of Methylenecyclohexanes With Differentiated Active Catalytic Species.Angewandte Chemie (International ed. in English) · 2026Article
- Anti-Markovnikov alkene hydroalkylation via iron photocatalysis.Nature catalysis · 2026Article
- Fe-electrocatalytic deoxygenative Giese reaction.Nature communications · 2025Article
- Iron Catalysts with Silyl-NHC Chelate Ligands: Controlling Factors for Hydroboration vs. Dehydrogenative Borylation of Olefins.Chemistry, an Asian journal · 2025Article
- Effective Alkyl-Alkyl Cross-Coupling with an Iron-Xantphos Catalyst: Mechanistic and Structural Insights.Angewandte Chemie (International ed. in English) · 2025Article
- Metal-Hydride C-C Cross-Coupling of Alkenes Through a Double Outer-Sphere Mechanism.The Journal of organic chemistry · 2024Review
- Enantioselective synthesis of chiral α,α-dialkyl indoles and related azoles by cobalt-catalyzed hydroalkylation and regioselectivity switch.Nature communications · 2024Article
- Electroreduction of unactivated alkenes using water as hydrogen source.Nature communications · 2024Article
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Authors and funding
4 authors.
Funding
Abstract
In terms of its abundance and its minimal toxicity, iron has advantages relative to other transition metals. Although alkyl-alkyl bond construction is central to organic synthesis, examples of iron-catalyzed alkyl-alkyl couplings of alkyl electrophiles are relatively sparse. Herein we report an iron catalyst that achieves cross-coupling reactions of alkyl electrophiles wherein olefins, in the presence of a hydrosilane, are used in place of alkylmetal reagents. Carbon-carbon bond formation proceeds at room temperature, and the method employs commercially available components (Fe(OAc)
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