ArticleChemical science2023
Disulfide radical anion as a super-reductant in biology and photoredox chemistry.
Article in Chemical science, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 13 papers.
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Who cites it
13 citing papers in PubMed.
- Mechanistic Insights into Mercury Photoreduction: Effects of Dissolved Organic Matter and Inorganic Carbon in Seawater.Environmental science & technology · 2026Article
- Deazaalloxazines - Flavin Derivatives That Provide Reductive Photoredox Catalysis with Inert Substrates.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Stepwise and reversible assembly of [2Fe-2S] rhombs to [8Fe-8S] clusters and their topological interconversions.Nature chemistry · 2025Article
- Molecular Design Considerations for Azobenzene Anolytes.ACS omega · 2025Article
- Discovery of the selenium-containing antioxidant ovoselenol derived from convergent evolution.Nature chemistry · 2024Article
- Stabilized Carbon-Centered Radical-Mediated Carbosulfenylation of Styrenes: Modular Synthesis of Sulfur-Containing Glycine and Peptide Derivatives.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- A DFT study on the heterolytic bond cleavage of hydrazones under cathodic conditions in acetonitrile.Journal of molecular modeling · 2024Article
- Ecotoxicity Assessment of α-Amino Acid-Derived Polyamidoamines Using Zebrafish as a Vertebrate Model.Polymers · 2024Article
- Metal-cation-induced shifts in thiolate redox and reduced sulfur speciation.Chemical science · 2024Article
- Crystal structure of 4,4'-(disulfanedi-yl)dipyridinium chloride triiodide.Acta crystallographica. Section E, Crystallographic communications · 2024Article
- Protein engineering a PhotoRNR chimera based on a unifying evolutionary apparatus among the natural classes of ribonucleotide reductases.Proceedings of the National Academy of Sciences of the United States of America · 2024Article
- Ovoselenol, a Selenium-containing Antioxidant Derived from Convergent Evolution.bioRxiv : the preprint server for biology · 2024Article
- Radical Reactions in Organic Synthesis: Exploring in-, on-, and with-Water Methods.Molecules (Basel, Switzerland) · 2024Review
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Authors and funding
4 authors.
Funding
Abstract
Disulfides are involved in a broad range of radical-based synthetic organic and biochemical transformations. In particular, the reduction of a disulfide to the corresponding radical anion, followed by S-S bond cleavage to yield a thiyl radical and a thiolate anion plays critical roles in radical-based photoredox transformations and the disulfide radical anion in conjunction with a proton donor, mediates the enzymatic synthesis of deoxynucleotides from nucleotides within the active site of the enzyme, ribonucleotide reductase (RNR). To gain fundamental thermodynamic insight into these reactions, we have performed experimental measurements to furnish the transfer coefficient from which the standard
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