ArticleNature communications2023
Hierarchical conductive metal-organic framework films enabling efficient interfacial mass transfer.
Article in Nature communications, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 20 papers.
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Who cites it
20 citing papers in PubMed.
- On-Water Surface Synthesis of 2D Conjugated Metal-Organic Framework Films With Controllable Layer Orientation Enabling High-Performance Chemiresistive Sensing.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Solvent dehydration with structurally engineered nanoporous graphene oxide membranes.Nature communications · 2026Article
- Highly modular conductive threads for multiplexed detection of hazardous gases.Nature communications · 2026Article
- Guest-induced porous gating of a fluorescent nonporous adaptive crystal for efficient radioactive iodine sorption.Nature communications · 2026Article
- Gas vortex discovery in butterfly microcavities for constructing ultrasensitive gas sensors.Science advances · 2026Article
- Skin-Integrated Soft Wearable XR Interfaces for Seamless and Realistic User Experience.Chemical reviews · 2025Review
- Highly Sensitive and Selective Zinc-Based Metal-Organic Framework Derivatives Gas Sensors for Trace HACS sensors · 2025Article
- Metal-Organic Framework-Based Chemiresistive Array Paired with Machine Learning Algorithms for the Detection and Differentiation of Toxic Gases.ACS sensors · 2025Article
- Ultrasensitive and Selective Fluorescent Sensor for 5-Hydroxymethylfurfural Based on a Molecularly Imprinted Polymeric Nanocomposite.Polymers · 2025Article
- Harnessing Microfluidics for the Effective and Precise Synthesis of Advanced Materials.Micromachines · 2025Review
- Pyrazine-Embedded 2D Conjugated Metal-Organic Framework with Quasi-Honeycomb Lattice for High-Capacitance Lithium-Ion Storage.Angewandte Chemie (International ed. in English) · 2025Article
- An aggregation-induced conformation locking strategy facilitates the activation of lipase biocatalyst.Nature communications · 2025Article
- Synthesizing Conductive Metal-Organic Framework Nanosheets for High-Performing Chemiresistive Sensors.ACS applied materials & interfaces · 2025Article
- Metal Exchange in Thioguanosine Coordination Polymers of Gold (I) and Silver (I).Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Artificial olfactory memory system based on conductive metal-organic frameworks.Nature communications · 2024Article
- Controllable Synthesis of Manganese Organic Phosphate with Different Morphologies and Their Derivatives for Supercapacitors.Molecules (Basel, Switzerland) · 2024Article
- Modulation between capacitor and conductor for a redox-active 2D bis(terpyridine)cobalt(II) nanosheet via anion-exchange.Communications chemistry · 2024Article
- Rational Construction of Two-Dimensional Conjugated Metal-Organic Frameworks (2D c-MOFs) for Electronics and Beyond.Accounts of chemical research · 2024Article
- Constructing ordered and tunable extrinsic porosity in covalent organic frameworks via water-mediated soft-template strategy.Nature communications · 2024Article
- High-Performance Room Temperature Ammonia Sensors Based on Pure Organic Molecules Featuring B-N Covalent Bond.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
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Authors and funding
18 authors.
Funding
Abstract
Heterogeneous reactions associated with porous solid films are ubiquitous and play an important role in both nature and industrial processes. However, due to the no-slip boundary condition in pressure-driven flows, the interfacial mass transfer between the porous solid surface and the environment is largely limited to slow molecular diffusion, which severely hinders the enhancement of heterogeneous reaction kinetics. Herein, we report a hierarchical-structure-accelerated interfacial dynamic strategy to improve interfacial gas transfer on hierarchical conductive metal-organic framework (c-MOF) films. Hierarchical c-MOF films are synthesized via the in-situ transformation of insulating MOF film precursors using π-conjugated ligands and comprise both a nanoporous shell and hollow inner voids. The introduction of hollow structures in the c-MOF films enables an increase of gas permeability, thus enhancing the motion velocity of gas molecules toward the c-MOF film surface, which is more than 8.0-fold higher than that of bulk-type film. The c-MOF film-based chemiresistive sensor exhibits a faster response towards ammonia than other reported chemiresistive ammonia sensors at room temperature and a response speed 10 times faster than that of the bulk-type film.
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