ArticleScience advances2023
Jamming and depletion in extremely bidisperse mixtures of microscale emulsions and nanoemulsions.
Article in Science advances, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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Who cites it
3 citing papers in PubMed.
- Non-Laplacian air-gap electrostatics for high-field oil-water nanoemulsion separation.Science advances · 2025Article
- Assessing depletion attractions between colloidal nanocrystals.Science advances · 2025Article
- Elasticity Mapping of Colloidal Glasses Reveals the Interplay between Mesoscopic Order and Granular Mechanics.Small methods · 2025Article
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Authors and funding
2 authors.
Funding
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Abstract
While much attention has been given to jamming of granular and colloidal particles having monomodal size distributions, jamming of systems having more complex size distributions remains an interesting direction. We create concentrated, disordered binary mixtures of size-fractionated nanoscale and microscale oil-in-water emulsions, which are stabilized by the same common ionic surfactant, and measure the optical transport properties, microscale droplet dynamics, and mechanical shear rheological properties of these mixtures over a wide range of relative and total droplet volume fractions. Simple effective medium theories do not explain all of our observations. Instead, we show that our measurements are consistent with more complex collective behavior in extremely bidisperse systems, involving an effective continuous phase that governs nanodroplet jamming, as well as depletion attractions between microscale droplets induced by nanoscale droplets.
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