Evidence map›Paper›PMID 37369076›Full record

ArticleInorganic chemistry2023

Homoleptic Fe(III) and Fe(IV) Complexes of a Dianionic C

Serhii Tretiakov, Martin Lutz, Charles James Titus, Frank de Groot, Joscha Nehrkorn, Thomas Lohmiller, Karsten Holldack, Alexander Schnegg, Maxime François Xavier Tarrago, Peng Zhang and 5 more

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Inorganic chemistry, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

15 authors.

Serhii TretiakovOrganic Chemistry & Catalysis, Institute for Sustainable and Circular Chemistry, Utrecht University, 3584 CG Utrecht, The Netherlands.
Martin LutzStructural Biochemistry, Bijvoet Centre for Biomolecular Research, Faculty of Science, Utrecht University, 3584 CG Utrecht, The Netherlands.
Charles James TitusDepartment of Physics, Stanford University, Stanford, California 94305, United States.
Frank de GrootMaterials Chemistry & Catalysis, Debye Institute for Materials Science, Utrecht University, 3584 CG Utrecht, The Netherlands.ORCID 0000-0002-1340-2186
Joscha NehrkornMax-Planck-Institute for Chemical Energy Conversion, EPR Research Group, 45470 Mülheim/Ruhr, Germany.
Thomas LohmillerDepartment Spins in Energy Conversion and Quantum Information Science, Helmholtz Zentrum Berlin für Materialien und Energie GmbH, EPR4 Energy Joint Lab, 12489 Berlin, Germany.ORCID 0000-0003-0373-1506
Karsten HolldackDepartment of Optics and Beamlines, Helmholtz Zentrum Berlin für Materialien und Energie GmbH, 12489 Berlin, Germany.
Alexander SchneggMax-Planck-Institute for Chemical Energy Conversion, EPR Research Group, 45470 Mülheim/Ruhr, Germany.ORCID 0000-0002-2362-0638
Maxime François Xavier TarragoDepartment of Molecular Theory and Spectroscopy, Max Planck Institut für Kohlenforschung, 45470 Mülheim/Ruhr, Germany.
Peng ZhangState Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, P. R. China.
Shengfa YeState Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, P. R. China.ORCID 0000-0001-9747-1412
Dmitry AleshinA.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilova Street 28, Moscow 119991, Russia.
Alexander PavlovA.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilova Street 28, Moscow 119991, Russia.
Valentin NovikovMoscow Institute of Physics and Technology, Institutskiy per., 9, Dolgoprudny, Moscow 119991, Russia.ORCID 0000-0002-0225-0594
Marc-Etienne MoretOrganic Chemistry & Catalysis, Institute for Sustainable and Circular Chemistry, Utrecht University, 3584 CG Utrecht, The Netherlands.ORCID 0000-0002-3137-6073

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

High-valent iron species have been implicated as key intermediates in catalytic oxidation reactions, both in biological and synthetic systems. Many heteroleptic Fe(IV) complexes have now been prepared and characterized, especially using strongly π-donating oxo, imido, or nitrido ligands. On the other hand, homoleptic examples are scarce. Herein, we investigate the redox chemistry of iron complexes of the dianonic tris-skatylmethylphosphonium (TSMP

Identifiers

PMID37369076
PMCPMC10336972

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.