Evidence map›Paper›PMID 37363871›Full record

ReviewEnvironmental science & technology2023

Critical Review on Bromate Formation during Ozonation and Control Options for Its Minimization.

Christina M Morrison, Samantha Hogard, Robert Pearce, Aarthi Mohan, Aleksey N Pisarenko, Eric R V Dickenson, Urs von Gunten, Eric C Wert

Open access · bronzeAbstract readReview
In one paragraph

Review in Environmental science & technology, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 14 papers, 1 of them a synthesis that pooled it.

0numbers the graph read from it
0cells of the map it votes in
14citing papers in PubMed, 1 pooled it
12.2field-weighted citation impact, top 1% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

14 citing papers in PubMed, 1 synthesis or guideline pooled it, 106 citations in OpenAlex.

  1. Pooled it
  2. Article
  3. Ozonation Eliminates Viable but Not CulturablePathogens (Basel, Switzerland) · 2026
    Article
  4. Advances in Physicochemical and Biological Treatment of Textile Wastewater: An Applied Review of Methods, Technologies, and Costs.Water environment research : a research publication of the Water Environment Federation · 2026
    Review
  5. Article
  6. Article
  7. Review
  8. Article
  9. Review
  10. Article
  11. Review
  12. Article
  13. Bromate Formation and Control During Ozonation in Advanced Wastewater Purification for Potable Reuse.Water environment research : a research publication of the Water Environment Federation · 2026
    Article
  14. Hybrid modelling framework for ozonation and biological activated carbon in tertiary wastewater treatment.Water science and technology : a journal of the International Association on Water Pollution Research · 2024
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors at 3 institutions in 2 countries.

Christina M MorrisonSouthern Nevada Water Authority (SNWA), P.O. Box 99954, Las Vegas, Nevada 89193-9954, United States.ORCID 0000-0001-8145-428X
Samantha HogardHampton Roads Sanitation District, P.O. Box 5911, Virginia Beach, Virginia 23471-0911, United States.ORCID 0000-0001-9364-7257
Robert PearceHampton Roads Sanitation District, P.O. Box 5911, Virginia Beach, Virginia 23471-0911, United States.
Aarthi MohanSouthern Nevada Water Authority (SNWA), P.O. Box 99954, Las Vegas, Nevada 89193-9954, United States.ORCID 0000-0002-1540-7757
Aleksey N PisarenkoTrussell Technologies, Inc., 380 Stevens Avenue, Suite 212, Solana Beach, California 92075, United States.
Eric R V DickensonSouthern Nevada Water Authority (SNWA), P.O. Box 99954, Las Vegas, Nevada 89193-9954, United States.ORCID 0000-0003-2341-4997
Urs von GuntenEawag, Swiss Federal Institute of Aquatic Science and Technology, Ueberlandstrasse 133, CH-8600 Dubendorf, Switzerland.ORCID 0000-0001-6852-8977
Eric C WertSouthern Nevada Water Authority (SNWA), P.O. Box 99954, Las Vegas, Nevada 89193-9954, United States.ORCID 0000-0001-5587-4635
Southern Nevada Water Authority · USHampton Roads Sanitation District · USÉcole Polytechnique Fédérale de Lausanne · CH

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Ozone is a commonly applied disinfectant and oxidant in drinking water and has more recently been implemented for enhanced municipal wastewater treatment for potable reuse and ecosystem protection. One drawback is the potential formation of bromate, a possible human carcinogen with a strict drinking water standard of 10 μg/L. The formation of bromate from bromide during ozonation is complex and involves reactions with both ozone and secondary oxidants formed from ozone decomposition, i.e., hydroxyl radical. The underlying mechanism has been elucidated over the past several decades, and the extent of many parallel reactions occurring with either ozone or hydroxyl radicals depends strongly on the concentration, type of dissolved organic matter (DOM), and carbonate. On the basis of mechanistic considerations, several approaches minimizing bromate formation during ozonation can be applied. Removal of bromate after ozonation is less feasible. We recommend that bromate control strategies be prioritized in the following order: (1) control bromide discharge at the source and ensure optimal ozone mass-transfer design to minimize bromate formation, (2) minimize bromate formation during ozonation by chemical control strategies, such as ammonium with or without chlorine addition or hydrogen peroxide addition, which interfere with specific bromate formation steps and/or mask bromide, (3) implement a pretreatment strategy to reduce bromide and/or DOM prior to ozonation, and (4) assess the suitability of ozonation altogether or utilize a downstream treatment process that may already be in place, such as reverse osmosis, for post-ozone bromate abatement. A one-size-fits-all approach to bromate control does not exist, and treatment objectives, such as disinfection and micropollutant abatement, must also be considered.

Indexed as

Drinking WaterOzoneWater Pollutants, ChemicalWater PurificationBromatesBromidesEcosystemHumansHydroxyl RadicalOxidantsBromatesBromidesDrinking WaterHydroxyl RadicalOxidantsOzoneWater Pollutants, Chemicalbromatedissolved organic matterhuman carcinogenozonation

Identifiers

PMID37363871
PMCPMC10690720
OpenAlexW4382050169

What OpenQuestion holds

Textmetadata
LicenceCC BY-NC-ND
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.