ArticleJournal of the American Chemical Society2023
Water Harvesting at the Single-Crystal Level.
Article in Journal of the American Chemical Society, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.
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Who cites it
10 citing papers in PubMed, 46 citations in OpenAlex.
- Scalable hierarchical textile fibers toward personalized wearable atmospheric water harvesting.Science advances · 2026Article
- Unraveling Water Sorption in Single-Crystal MOFs: Insights from Spectroscopy and Modeling on the Role of Structure, Composition, and Guest Molecules.Small (Weinheim an der Bergstrasse, Germany) · 2026Article
- Crystallization-assisted water adsorption in amorphous molecular adsorbents.Nature communications · 2026Article
- Hierarchically MOF-Based Porous Monolith Composites for Atmospheric Water Harvesting.Advanced materials (Deerfield Beach, Fla.) · 2026Review
- Advancements in Understanding the Physicochemical Properties of Reticular Materials: An In Situ and Operando Spectroscopic Perspective.Advanced materials (Deerfield Beach, Fla.) · 2025Review
- Retrospective Review on Reticular Materials: Facts and Figures Over the Last 30 Years.Advanced materials (Deerfield Beach, Fla.) · 2025Article
- Decoding the Water Harvesting Mechanism of MIL-100(Fe) Across Short- and Long-Range Length Scales.Journal of the American Chemical Society · 2025Article
- Small Rotations, Big Effects: Lessons from Water Adsorption in NU-1000.The journal of physical chemistry. C, Nanomaterials and interfaces · 2025Article
- Water motifs in zirconium metal-organic frameworks induced by nanoconfinement and hydrophilic adsorption sites.Nature communications · 2024Article
- Spontaneous water oozing of a soft drain bed via energy-free atmospheric water harvesting.iScience · 2024Article
Corrections and comments
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Authors and funding
7 authors at 4 institutions in 4 countries.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Metal-organic frameworks (MOFs) have emerged as a class of porous materials with facile uptake and release of water, turning them into excellent substrates for real-world atmospheric water harvesting applications. The performance of different MOF systems was experimentally characterized at the bulk level by assessing the total amount of water taken up and the release kinetics, leaving the question behind of what the upper limit of the pristine materials actually is. Moreover, recent devices rely on fluidized bed reactors that exploit the harvesting capacities of MOFs at the single-crystal (SC) level. In this publication, we present a novel methodology based on Raman spectroscopy, for acquiring water adsorption isotherms and kinetic curves with a sub-micrometer resolution that provides valuable insights into the material behavior probing the pristine MOF at the SC level. We investigated isolated MOF-801 particles in situ and could dissect contributions of intra- and inter-particle effects on the water harvesting performance of MOF-801 via adsorption-desorption isotherms and kinetic curves. Using spontaneous Raman spectroscopy, we found an almost 20-fold faster uptake for the undisturbed crystalline material. Correlative imaging based on four-wave mixing and coherent anti-Stokes Raman scattering further localized the uptaken water inside MOF-801 and identified inter-particle condensation as the main source for the discrepancies between the performance at the bulk and SC level. Our studies determined an upper limit of around 91.9 L/kg
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.