Evidence map›Paper›PMID 37350840›Full record

ArticleChemical science2023

Sodium mediated deprotonative borylation of arenes using sterically demanding B(CH

Andreu Tortajada, Leonie J Bole, Manting Mu, Martin Stanford, Marconi N Peñas-Defrutos, Max García-Melchor, Eva Hevia

Abstract read
In one paragraph

Article in Chemical science, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.

0numbers the graph read from it
0cells of the map it votes in
4citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

4 citing papers in PubMed.

  1. Calcium Alkynyl(hydrido)zincates.Organometallics · 2026
    Article
  2. Alkali-Metal Base Catalyzed Electrocyclization of Isoprene Derivatives.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026
    Article
  3. Crown Ether Supported Alkali Metal Phosphides: Synthesis, Structures and Bonding.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025
    Article
  4. Functionalization of Pyridines at the C4 Position via Metalation and Capture.Angewandte Chemie (International ed. in English) · 2025
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Andreu TortajadaDepartment für Chemie und Biochemie, Universität Bern Freiestrasse 3 3012 Bern Switzerland eva.hevia@unibe.ch.ORCID https://orcid.org/0000-0002-2635-8030
Leonie J BoleDepartment für Chemie und Biochemie, Universität Bern Freiestrasse 3 3012 Bern Switzerland eva.hevia@unibe.ch.
Manting MuSchool of Chemistry, CRANN and AMBER Research Centres, Trinity College Dublin College Green Dublin 2 Ireland garciamm@tcd.ie.
Martin StanfordDepartment für Chemie und Biochemie, Universität Bern Freiestrasse 3 3012 Bern Switzerland eva.hevia@unibe.ch.ORCID https://orcid.org/0000-0003-1842-3020
Marconi N Peñas-DefrutosSchool of Chemistry, CRANN and AMBER Research Centres, Trinity College Dublin College Green Dublin 2 Ireland garciamm@tcd.ie.ORCID https://orcid.org/0000-0003-4804-8751
Max García-MelchorSchool of Chemistry, CRANN and AMBER Research Centres, Trinity College Dublin College Green Dublin 2 Ireland garciamm@tcd.ie.ORCID https://orcid.org/0000-0003-1348-4692
Eva HeviaDepartment für Chemie und Biochemie, Universität Bern Freiestrasse 3 3012 Bern Switzerland eva.hevia@unibe.ch.ORCID https://orcid.org/0000-0002-3998-7506

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The deprotonative metalation of organic molecules has become a convenient route to prepare functionalised aromatic substrates. Amongst the different metallating reagents available, sodium bases have recently emerged as a more sustainable and powerful alternative to their lithium analogues. Here we report the study of the sterically demanding electrophilic trap B(CH

Identifiers

PMID37350840
PMCPMC10283504

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.