ReviewNature reviews. Chemistry2023
Radical approaches to C-S bonds.
Review in Nature reviews. Chemistry, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 19 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
19 citing papers in PubMed.
- Highly chemoselective access to alkyl-sulfur compounds via NNature chemistry · 2026Article
- From Preinstalled AIEgens to In Situ-Generated AIE Motifs: Photo-Triggered Dynamic C = S Bond Formation in Polymers for 4D Luminescence Encryption.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- 4-Fluorophenyl Tagging as a Diagnostic Tool for Monitoring Sulfur Oxidation States via 19F NMR.The Journal of organic chemistry · 2026Article
- Catalytic Enantioselective Construction of Carbon-Sulfur Bonds: Recent Advances and Future Perspectives.Molecules (Basel, Switzerland) · 2026Review
- Photoredox-Catalyzed Chem- and Stereoselective Thiosulfonylation of Cyclopropylamides.Angewandte Chemie (International ed. in English) · 2026Article
- Multicomponent Photochemical Assembly of C(spACS organic & inorganic Au · 2026Article
- Counterion-enabled divergent reactivity in dinuclear gold photoredox catalysis.Nature communications · 2026Article
- Revealing and Exploiting the Biochemistry ofBiochemistry · 2026Review
- Three-component synthesis of β-thio tertiary alkylamines from simple alkenes via SScience advances · 2026Article
- Iron-mediated C(spTetrahedron · 2025Article
- Photoactivatable Electrophilic Glycosylselenosulfonates for Ultrafast Modification of Alkynes and Thiols.ACS central science · 2025Article
- A Needle-Like HAdvanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Asymmetric Enantio-complementary Synthesis of Thioethers via Ene-Reductase-Catalyzed C-C Bond Formation.Journal of the American Chemical Society · 2025Article
- Reductive sulfinylation by nucleophilic chain isomerization of sulfonylpyridinium.Nature communications · 2025Article
- C(spAngewandte Chemie (International ed. in English) · 2024Article
- Advancements in visible-light-induced reactions via alkenyl radical intermediates.Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology · 2024Review
- Cross-Electrophile Coupling of Benzyl Halides and Disulfides Catalyzed by Iron.Journal of the American Chemical Society · 2024Article
- Direct conversion of carboxylic acids to free thiolsChemical science · 2024Article
- Photochemical halogen-bonding assisted carbothiophosphorylation reactions of alkenyl and 1,3-dienyl bromides.Chemical science · 2023Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
2 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Organosulfur functionalities are ubiquitous in nature, pharmaceuticals, agrochemicals, materials and flavourants. Historically, these moieties were introduced almost exclusively using ionic chemistry; however, radical-based methods for the installation of sulfur-based functional groups have recently come to the fore. These radical methods have enabled their late-stage introduction into complex molecules, avoiding the need to preserve labile organosulfur moieties through multistep synthetic sequences. Here, we discuss homolytic C-S bond-forming processes, with a particular emphasis on radical substitution approaches to sulfide, disulfide and sulfinyl products, and the use of sulfur dioxide and its surrogates to build sulfonyl products. We also highlight the mechanistic considerations that we hope will guide further development of radical-based strategies compatible with the various organosulfur moieties that feature in modern chemistry.
Identifiers
37344618What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.