ArticleNature communications2023
A fluorinated cation introduces new interphasial chemistries to enable high-voltage lithium metal batteries.
Article in Nature communications, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.
What it found
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The trial behind it
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Who cites it
10 citing papers in PubMed.
- Medium-fluorination carbonate electrolytes for stable 4.6 V lithium metal batteries.Chemical science · 2026Article
- Electrostatic regulation of solvation chemistry enables ampere-hour-scale high-energy lithium metal batteries.Nature nanotechnology · 2026Article
- Promoting Electrochemical Reactions with Dual-Atom Catalysts for High-Rate Lithium-Sulfur Batteries.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Toward Zero-Excess Alkali Metal Batteries: Bridging Experimental and Computational Insights.Advanced materials (Deerfield Beach, Fla.) · 2025Review
- Article
- Unveiling cathode catalysis of fluorinated electrolyte additives for high-performance Na-ClNational science review · 2025Article
- Stereoisomerism of multi-functional electrolyte additives for initially anodeless aqueous zinc metal batteries.Nature communications · 2025Article
- A Recyclable Inert Inorganic Framework Assisted Solid-State Electrolyte for Long-Life Aluminum Ion Batteries.ACS central science · 2025Article
- High-Energy LiNiOAdvanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- Robust battery interphases from dilute fluorinated cations.Energy & environmental science · 2024Article
Corrections and comments
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Authors and funding
11 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Fluorides have been identified as a key ingredient in interphases supporting aggressive battery chemistries. While the precursor for these fluorides must be pre-stored in electrolyte components and only delivered at extreme potentials, the chemical source of fluorine so far has been confined to either negatively-charge anions or fluorinated molecules, whose presence in the inner-Helmholtz layer of electrodes, and consequently their contribution to the interphasial chemistry, is restricted. To pre-store fluorine source on positive-charged species, here we show a cation that carries fluorine in its structure is synthesized and its contribution to interphasial chemistry is explored for the very first time. An electrolyte carrying fluorine in both cation and anion brings unprecedented interphasial chemistries that translate into superior battery performance of a lithium-metal battery, including high Coulombic efficiency of up to 99.98%, and Li
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.