ArticleJournal of the American Chemical Society2023
Saturated Linkers in Two-Dimensional Covalent Organic Frameworks Boost Their Luminescence.
Article in Journal of the American Chemical Society, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 22 papers.
What it found
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Who cites it
22 citing papers in PubMed, 101 citations in OpenAlex.
- Guest-Induced Vibration Locking and Fluorescence Switching in a Pyrene-Functionalized Covalent Organic Framework (COF) for Perfluorooctanoic Acid (PFOA) Recognition.Journal of the American Chemical Society · 2026Article
- Gating hole back-transfer with molecular spacers programs rapid micropollutant decontamination.Nature communications · 2026Article
- Emergence of Chiral Defective Pores Through Chiral Linker Exchange in Nonchiral MOFs for Enantioselective Recognition.Angewandte Chemie (International ed. in English) · 2026Article
- Breaking π-π Stacking in One-Dimensional Covalent Organic Frameworks.Angewandte Chemie (International ed. in English) · 2026Article
- Luminescent Covalent-Organic Frameworks: Design Strategies, Photophysical Mechanisms, and Applications.Small methods · 2026Review
- Imine Linkage Isomerism in Layer-Entangled Three-Dimensional Covalent Organic Frameworks Modulates Fluorescent Sensing.Angewandte Chemie (International ed. in English) · 2026Article
- Potential of Covalent Organic Framework in Pharmacy and Biomedicine: Influence of Structure on Properties and Applications.ChemMedChem · 2026Review
- Pressure-driven steric hindrance engineering for maximizing photoluminescence in covalent organic frameworks.Science advances · 2026Article
- Aminal-linked Covalent Organic Frameworks for Light Energy Upconversion.Angewandte Chemie (International ed. in English) · 2026Article
- Deuteration Induced Electron-Phonon Coupling Modulation: Suppressing Energy Dissipation and Enhancing Carrier Separation in Organic Photocatalysis.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Fascinating Frontier, Nanoarchitectonics, as Method for Everything in Materials Science.Materials (Basel, Switzerland) · 2025Review
- Boosting the brightness of aggregation-caused quenching chromophore-based covalent organic frameworks via energy level matching strategy.Nature communications · 2025Article
- Discovery of highly fluorescent covalent organic frameworks through AI-assisted iterative experiment-learning cycles.Nature chemistry · 2025Article
- Reductive Transformation of Imine Covalent Organic Frameworks into Emissive Polymers: Insights into Emission Quenching.Chemistry of materials : a publication of the American Chemical Society · 2025Article
- Homochiral versus Racemic 2D Covalent Organic Frameworks.Journal of the American Chemical Society · 2025Article
- Catalytic Ethylene Oligomerization over Imine-Linked Covalent-Organic Frameworks with Coordinative Ni(II) and Cr(III).ACS sustainable chemistry & engineering · 2025Article
- Interface preassembly oriented growth strategy towards flexible crystalline covalent organic framework films for OLEDs.Nature communications · 2025Article
- Layer-by-Layer Nanoarchitectonics: A Method for Everything in Layered Structures.Materials (Basel, Switzerland) · 2025Review
- Azatriangulene-Based Conductive C═C Linked Covalent Organic Frameworks with Near-Infrared Emission.Advanced materials (Deerfield Beach, Fla.) · 2024Article
- Photons, Excitons, and Electrons in Covalent Organic Frameworks.Journal of the American Chemical Society · 2024Review
Corrections and comments
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Authors and funding
11 authors at 6 institutions in 4 countries.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The development of highly luminescent two-dimensional covalent organic frameworks (COFs) for sensing applications remains challenging. To suppress commonly observed photoluminescence quenching of COFs, we propose a strategy involving interrupting the intralayer conjugation and interlayer interactions using cyclohexane as the linker unit. By variation of the building block structures, imine-bonded COFs with various topologies and porosities are obtained. Experimental and theoretical analyses of these COFs disclose high crystallinity and large interlayer distances, demonstrating enhanced emission with record-high photoluminescence quantum yields of up to 57% in the solid state. The resulting cyclohexane-linked COF also exhibits excellent sensing performance for the trace recognition of Fe
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.