ArticleChemistry (Weinheim an der Bergstrasse, Germany)2023
A Blueprint for the Stabilization of Sub-Valent Alkaline Earth Complexes.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
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4 citing papers in PubMed.
- Synthesis, characterization and reactivity of a series of alkaline earth and rare earth iminophosphoranomethanide complexes.Communications chemistry · 2025Article
- Heavy Alkaline Earth Cyclic (Alkyl)(Amino)Carbene Complexes Supported by Aryl-Silyl Amides.Inorganic chemistry · 2024Article
- Mechanochemical Synthesis, Characterization and Reactivity of a Room Temperature Stable Calcium Electride.Journal of the American Chemical Society · 2024Article
- A Blueprint for the Stabilization of Sub-Valent Alkaline Earth Complexes.Chemistry (Weinheim an der Bergstrasse, Germany) · 2023Article
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6 authors.
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Abstract
The study of sub-valent Group 2 chemistry is a relatively new research field, being established in 2007 with the report of the first Mg(I) dimers. These species are stabilized by the formation of a Mg-Mg covalent bond; however, the extension of this chemistry to heavier alkaline earth (AE) metals has been frustrated by significant synthetic challenges, primarily associated with the instability of heavy AE-AE interactions. Here we present a new blueprint for the stabilization of heavy AE(I) complexes, based upon the reduction of AE(II) precursors with planar coordination geometries. We report the synthesis and structural characterisation of homoleptic trigonal planar AE(II) complexes of the monodentate amides {N(SiMe
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