Evidence map›Paper›PMID 37325154›Full record

ArticleChemical science2023

Light-regulating chirality of metallacages featuring dithienylethene switches.

Shaomeng Guo, Mengqi Li, Honglong Hu, Ting Xu, Hancheng Xi, Wei-Hong Zhu

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PubMed Full text at PMC Publisher
In one paragraph

Article in Chemical science, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors.

Shaomeng GuoKey Laboratory for Advanced Materials, Joint International Research Laboratory of Precision Chemistry, Molecular Engineering Feringa Nobel Prize Scientist Joint Research Center, Shanghai Key Laboratory of Functional Materials Chemistry, Institute of Fine Chemicals, School of Chemistry and Molecular Engineering, East China University of Science and Technology 200237 China whzhu@ecust.edu.cn.
Mengqi LiKey Laboratory for Advanced Materials, Joint International Research Laboratory of Precision Chemistry, Molecular Engineering Feringa Nobel Prize Scientist Joint Research Center, Shanghai Key Laboratory of Functional Materials Chemistry, Institute of Fine Chemicals, School of Chemistry and Molecular Engineering, East China University of Science and Technology 200237 China whzhu@ecust.edu.cn.
Honglong HuKey Laboratory for Advanced Materials, Joint International Research Laboratory of Precision Chemistry, Molecular Engineering Feringa Nobel Prize Scientist Joint Research Center, Shanghai Key Laboratory of Functional Materials Chemistry, Institute of Fine Chemicals, School of Chemistry and Molecular Engineering, East China University of Science and Technology 200237 China whzhu@ecust.edu.cn.
Ting XuKey Laboratory for Advanced Materials, Joint International Research Laboratory of Precision Chemistry, Molecular Engineering Feringa Nobel Prize Scientist Joint Research Center, Shanghai Key Laboratory of Functional Materials Chemistry, Institute of Fine Chemicals, School of Chemistry and Molecular Engineering, East China University of Science and Technology 200237 China whzhu@ecust.edu.cn.
Hancheng XiKey Laboratory for Advanced Materials, Joint International Research Laboratory of Precision Chemistry, Molecular Engineering Feringa Nobel Prize Scientist Joint Research Center, Shanghai Key Laboratory of Functional Materials Chemistry, Institute of Fine Chemicals, School of Chemistry and Molecular Engineering, East China University of Science and Technology 200237 China whzhu@ecust.edu.cn.
Wei-Hong ZhuKey Laboratory for Advanced Materials, Joint International Research Laboratory of Precision Chemistry, Molecular Engineering Feringa Nobel Prize Scientist Joint Research Center, Shanghai Key Laboratory of Functional Materials Chemistry, Institute of Fine Chemicals, School of Chemistry and Molecular Engineering, East China University of Science and Technology 200237 China whzhu@ecust.edu.cn.ORCID https://orcid.org/0000-0001-9103-166X

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Dynamic chiral superstructures are of vital importance for understanding the organization and function of chirality in biological systems. However, achieving high conversion efficiency for photoswitches in nanoconfined architectures remains challenging but fascinating. Herein, we report a series of dynamic chiral photoswitches based on supramolecular metallacages through the coordination-driven self-assembly of dithienylethene (DTE) units and octahedral zinc ions, thereby successfully achieving an ultrahigh photoconversion yield of 91.3% in nanosized cavities with a stepwise isomerization mechanism. Interestingly, the chiral inequality phenomenon is observed in metallacages, resulting from the intrinsic photoresponsive chirality in the closed form of the dithienylethene unit. Upon hierarchical organization, we establish a dynamic chiral system at the supramolecular level, featuring chiral transfer, amplification, induction, and manipulation. This study provides an intriguing idea to simplify and understand chiral science.

Identifiers

PMID37325154
PMCPMC10266469

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.