ArticleJournal of the American Chemical Society2023
Rational Design of Persistent Phosphorus-Centered Singlet Tetraradicals and Their Use in Small-Molecule Activation.
Article in Journal of the American Chemical Society, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 12 papers.
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Who cites it
12 citing papers in PubMed, 28 citations in OpenAlex.
- Bond and Antibond Resonances: A Unified Framework for Singlet Biradical Character.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Büchner-type ring expansion of aromatic main-group biradicaloids toward phosphorus radical-derived NIR-II photothermal materials.Chemical science · 2025Article
- Reactivity of Pnictaalumenes Towards 1,3-Dipole Molecules.Angewandte Chemie (International ed. in English) · 2025Article
- On the Facile Synthesis of Triazaarsoles Using Acyclic Precursors.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Unconventional Parahydrogen-Induced Hyperpolarization Effects in Chemistry and Catalysis: From Photoreactions to Enzymes.ACS catalysis · 2025Review
- Reaction of NHOs with Bisphosphanes - Designing Diradicaloids, Zwitterions and Radicals.Angewandte Chemie (International ed. in English) · 2025Article
- Isolation of a Staudinger-type Intermediate Utilizing a Five-Membered Phosphorus-Centered Biradicaloid.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Leap from Diradicals to Tetraradicals by Topological Control of π-Conjugation.The Journal of organic chemistry · 2024Article
- Hydrogen splitting at a single phosphorus centre and its use for hydrogenation.Nature chemistry · 2024Article
- Pathway to Polyradicals: A Planar and Fully π-Conjugated Organic Tetraradical(oid).The journal of physical chemistry letters · 2024Article
- Isolation of an Anionic Dicarbene Embedded SnAdvanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- Light-Driven Enantioselective Carbene-Catalyzed Radical-Radical Coupling.Angewandte Chemie (International ed. in English) · 2023Article
Corrections and comments
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Authors and funding
7 authors at 3 institutions in 2 countries.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Biradicals are important intermediates in the process of bond formation and breaking. While main-group-element-centered biradicals have been thoroughly studied, much less is known about tetraradicals, as their very low stability has hampered their isolation and use in small-molecule activation. Herein, we describe the search for persistent phosphorus-centered tetraradicals. Starting from an
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What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.