ArticleScience advances2023
Highly efficient and stable thermally activated delayed fluorescent palladium(II) complexes for organic light-emitting diodes.
Article in Science advances, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
What it found
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Who cites it
8 citing papers in PubMed.
- Stable Pincer Gold(III)-TADF Emitters with Extended Donor-Acceptor Separation for Efficient Vacuum-Deposited OLEDs with Operational Lifetime (LTAdvanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Iridium(III) Carbene Complexes Featuring Either Metal-to-Ligand Charge Transfer (MLCT) or Through-Space Charge Transfer (TSCT) Blue Luminescence.Angewandte Chemie (International ed. in English) · 2025Article
- Motivation on Intramolecular Through-Space Charge Transfer for the Realization of Thermally Activated Delayed Fluorescence (TADF)-Thermally Stimulated Delayed Phosphorescence (TSDP) in C^C^N Gold(III) Complexes and Their Applications in Organic Light-Emitting Devices.Journal of the American Chemical Society · 2025Article
- Enhanced Emitting Dipole Orientation Based on Asymmetric Iridium(III) Complexes for Efficient Saturated-Blue Phosphorescent OLEDs.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- Phosphorescent PdAdvanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- Shining New Light on Biological Systems: Luminescent Transition Metal Complexes for Bioimaging and Biosensing Applications.Chemical reviews · 2024Review
- Nonplanar structure accelerates reverse intersystem crossing of TADF emitters: nearly 40% EQE and relieved efficiency roll off.Chemical science · 2024Article
- Investigation of Electronic Structures of Triplet States Using Step-Scan Time-Resolved Fourier-Transform Near-Infrared Spectroscopy.The journal of physical chemistry letters · 2024Article
Corrections and comments
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Authors and funding
11 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Transition metal complexes exhibiting thermally activated delayed fluorescence (TADF) remain underdeveloped for organic light-emitting diodes (OLEDs). Here, we describe a design of TADF Pd(II) complexes featuring metal-perturbed intraligand charge-transfer excited states. Two orange- and red-emitting complexes with efficiencies of 82 and 89% and lifetimes of 2.19 and 0.97 μs have been developed. Combined transient spectroscopic and theoretical studies on one complex reveal a metal-perturbed fast intersystem crossing process. OLEDs using the Pd(II) complexes show maximum external quantum efficiencies of 27.5 to 31.4% and small roll-offs down to 1% at 1000 cd m
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.