ArticleNature communications2023
Trichalcogenasupersumanenes and its concave-convex supramolecular assembly with fullerenes.
Article in Nature communications, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
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Who cites it
7 citing papers in PubMed.
- N-Bordered Rylene Arches via Programmable Curved π-Extension.Nature communications · 2026Article
- Nanographenic bowls based on contorted hexabenzocoronene: Synthesis, structure, and supramolecular assembly with fullerene CScience advances · 2026Article
- N-Doped Nonalternant Molecular Bowl/Saddle Hybrids.Angewandte Chemie (International ed. in English) · 2025Article
- Precise Internal Postsynthetic Oxygen-Doping of Metallonanographenes.Precision chemistry · 2025Article
- Probing the Antiaromaticity and Coordination Chemistry of Bowl-Shaped Zinc(II) Norcorrole.Inorganic chemistry · 2024Article
- Cycl[2,2,4]azine-embedded non-alternant nanographenes containing fused antiaromatic azepine ring.Chemical science · 2024Article
- Recent advances in supramolecular fullerene chemistry.Chemical Society reviews · 2024Review
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Authors and funding
14 authors.
Funding
Abstract
Synthesis of buckybowls have stayed highly challenging due to the large structural strain caused by curved π surface. In this paper, we report the synthesis and properties of two trichalcogenasupersumanenes which three chalcogen (sulfur or selenium) atoms and three methylene groups bridge at the bay regions of hexa-peri-hexabenzocoronene. These trichalcogenasupersumanenes are synthesized quickly in three steps using an Aldol cyclotrimerization, a Scholl oxidative cyclization, and a Stille type reaction. X-ray crystallography analysis reveals that they encompass bowl diameters of 11.06 Å and 11.35 Å and bowl depths of 2.29 Å and 2.16 Å for the trithiasupersumanene and triselenosupersumanene, respectively. Furthermore, trithiasupersumanene derivative with methyl chains can form host-guest complexes with C
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