ArticleJournal of the American Chemical Society2023
High-Concentration Self-Assembly of Zirconium- and Hafnium-Based Metal-Organic Materials.
Article in Journal of the American Chemical Society, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 14 papers.
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Who cites it
14 citing papers in PubMed.
- Transitioning Formamide Solvothermal Syntheses of MOFs to Less Toxic Solvents.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- ZrChemical science · 2026Article
- Mechanism-Guided Precision Hydrolysis of Early Transition Metals to Access (Mixed-Metal) Oxo Clusters.Angewandte Chemie (International ed. in English) · 2026Article
- High-concentration aqueous synthesis of salicylate-based metal-organic frameworks.Journal of materials chemistry. A · 2025Article
- Nanoscale Porphyrin-Based Metal-Organic Frameworks for Enhanced Radiotherapy-Radiodynamic Therapy: A Comprehensive Review.Pharmaceutics · 2025Review
- Synthesis and Properties of Energetic MOFs Based on Bis(3-Nitro-1Molecules (Basel, Switzerland) · 2025Article
- Controlled Growth and Interconversion of Photoluminescent Metal-Organic Frameworks Under High-Concentration Conditions.Chemistry of materials : a publication of the American Chemical Society · 2025Article
- Cisplatin-loaded UiO-66-NHHeliyon · 2025Article
- Defect-Engineered Metal-Organic Frameworks as Bioinspired Heterogeneous Catalysts for Amide Bond Formation.Journal of the American Chemical Society · 2024Article
- Ultrafast synthesis of zirconium-porphyrin framework nanocrystals from alkoxide precursors.Cell reports. Physical science · 2024Article
- Cobalt(III) Halide Metal-Organic Frameworks Drive Catalytic Halogen Exchange.Journal of the American Chemical Society · 2024Article
- Kinetic Trapping of Photoluminescent Frameworks During High-Concentration Synthesis of Non-Emissive Metal-Organic Frameworks.Chemistry of materials : a publication of the American Chemical Society · 2023Article
- Simplifying the Synthesis of Metal-Organic Frameworks.Accounts of materials research · 2023Article
- MOFganic Chemistry: Challenges and Opportunities for Metal-Organic Frameworks in Synthetic Organic Chemistry.Chemistry of materials : a publication of the American Chemical Society · 2023Article
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Authors and funding
4 authors.
Funding
Abstract
Metal-organic frameworks (MOFs) are crystalline, porous solids constructed from organic linkers and inorganic nodes that are promising for applications in chemical separations, gas storage, and catalysis, among many others. However, a major roadblock to the widespread implementation of MOFs, including highly tunable and hydrolytically stable Zr- and Hf-based frameworks, is their benchtop-scalable synthesis, as MOFs are typically prepared under highly dilute (≤0.01 M) solvothermal conditions. This necessitates the use of liters of organic solvent to prepare only a few grams of MOF. Herein, we demonstrate that Zr- and Hf-based frameworks (eight examples) can self-assemble at much higher reaction concentrations than are typically utilized, up to 1.00 M in many cases. Combining stoichiometric amounts of Zr or Hf precursors with organic linkers at high concentrations yields highly crystalline and porous MOFs, as confirmed by powder X-ray diffraction (PXRD) and 77 K N
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Registered trials
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