ArticleNano letters2023
Mechanism of Water Intrusion into Flexible ZIF-8: Liquid Is Not Vapor.
Article in Nano letters, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
6 citing papers in PubMed.
- Article
- Crystallite Size Effects on the Heat of Water Intrusion/Extrusion into/from Metal-Organic Frameworks.The journal of physical chemistry letters · 2025Article
- Effects of Size and Porosity on the Hydrophobicity of Hierarchical Nanoparticles.Nano letters · 2025Article
- Flat-Histogram Monte Carlo Simulation of Water Adsorption in Metal-Organic Frameworks.The journal of physical chemistry. B · 2024Article
- Exploring the Heat of Water Intrusion into a Metal-Organic Framework by Experiment and Simulation.ACS applied materials & interfaces · 2024Article
- Effect of Crystallite Size on the Flexibility and Negative Compressibility of Hydrophobic Metal-Organic Frameworks.Nano letters · 2023Article
Corrections and comments
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Authors and funding
13 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Zeolitic Imidazolate Frameworks (ZIF) find application in storage and dissipation of mechanical energy. Their distinctive properties linked to their (sub)nanometer size and hydrophobicity allow for water intrusion only under high hydrostatic pressure. Here we focus on the popular ZIF-8 material investigating the intrusion mechanism in its nanoscale cages, which is the key to its rational exploitation in target applications. In this work, we used a joint experimental/theoretical approach combining in operando synchrotron experiments during high-pressure intrusion experiments, molecular dynamics simulations, and stochastic models to reveal that water intrusion into ZIF-8 occurs by a cascade filling of connected cages rather than a condensation process as previously assumed. The reported results allowed us to establish structure/function relations in this prototypical microporous material, representing an important step to devise design rules to synthesize porous media.
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Registered trials
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