ArticleChemical science2023
Isolation and redox reactivity of cerium complexes in four redox states.
Article in Chemical science, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
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Who cites it
9 citing papers in PubMed.
- A Neutral Dy(II) Bis(amide): Synthesis, Magnetism, and a PInorganic chemistry · 2025Article
- Tripodal Silanolate Ligands Expand [MoXJournal of the American Chemical Society · 2025Article
- Product Variation in Reactions of MIInorganic chemistry · 2025Article
- Tuning the Electronic Properties of Tetravalent Cerium Complexes via Ligand Derivatization.Inorganic chemistry · 2025Article
- Expanding the Coordination of f-Block Metals with Tris[2-(2-methoxyethoxy)ethyl]amine: From Molecular Complexes to Cage-like Structures.Inorganic chemistry · 2024Article
- Siloxide tripodal ligands as a scaffold for stabilizing lanthanides in the +4 oxidation state.Chemical science · 2024Article
- Molybdenum(VI) Nitrido Complexes with Tripodal Silanolate Ligands. Structure and Electronic Character of an Unsymmetrical Dimolybdenum μ-Nitrido Complex Formed by Incomplete Nitrogen Atom Transfer.Inorganic chemistry · 2024Article
- Tetravalent Cerium Alkyl and Benzyl Complexes.Journal of the American Chemical Society · 2024Article
- Rare Earths-The Answer to Everything.Molecules (Basel, Switzerland) · 2024Review
Corrections and comments
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Authors and funding
6 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The chemistry of lanthanides is limited to one electron transfer reactions due to the difficulty of accessing multiple oxidation states. Here we report that a redox-active ligand combining three siloxides with an arene ring in a tripodal ligand can stabilize cerium complexes in four different redox states and can promote multielectron redox reactivity in cerium complexes. Ce(iii) and Ce(iv) complexes [(LO
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Registered trials
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